Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Bis[N-(2-furylmeth-yl)ethane-1,2-di-amine]-bis-(perchlorato)copper(II).

ABSTRACT: In the title complex, [Cu(ClO(4))(2)(C(7)H(12)N(2)O)(2)], the Cu(II) ion lies on a crystallographic inversion centre. The coordination sphere around Cu(II) ion can be described as tetragonally distorted octa-hedral with two perchlorate O atoms occupying the apical positions and four N atoms from two N(1)-(2-furyl-methyl)ethane-1,2-diamine ligands in the basal plane.

SUBMITTER: Xiao W

PROVIDER: S-EPMC3120411 | biostudies-other | 2011 Jun

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

Bis[N-(2-furylmeth-yl)ethane-1,2-di-amine]-bis-(perchlorato)copper(II).

Xiao Wei W Li Shi-Rong SR Zhou Hong H Pan Zhi-Quan ZQ Huang Qimao Q

Acta crystallographica. Section E, Structure reports online 20110507 Pt 6

In the title complex, [Cu(ClO(4))(2)(C(7)H(12)N(2)O)(2)], the Cu(II) ion lies on a crystallographic inversion centre. The coordination sphere around Cu(II) ion can be described as tetragonally distorted octa-hedral with two perchlorate O atoms occupying the apical positions and four N atoms from two N(1)-(2-furyl-methyl)ethane-1,2-diamine ligands in the basal plane. ...[more]

PMID: 21754605

Similar Datasets

Acetato-chlorido[2,2'-(ethane-1,2-di-yl)di-1H-benzimidazole]-copper(II) monohydrate.

Project description:In the title complex, [Cu(CH(3)COO)Cl(C(16)H(14)N(4))]·H(2)O, the Cu(II) ion is five-coordinated by two N atoms from a 2,2'-(ethane-1,2-di-yl)di-1H-benzimidazole ligand, two O atoms from a chelating acetate ligand and one terminal monodentate Cl atom in a distorted square-pyramidal geometry. In the crystal, adjacent mol-ecules are linked through O-H⋯Cl, N-H⋯Cl, N-H⋯O and O-H⋯O hydrogen bonds into a three-dimensional network.

| S-EPMC3008101 | biostudies-literature

1,2-Bis(di-2-pyridylphosphino-yl)ethane.

Project description:The crystal structure of the title compound, C(22)H(20)N(4)O(2)P(2), consists of two independent half-mol-ecules, both of which lie on crystallographic inversion centres. There are no significant differences between the two mol-ecules.

| S-EPMC2968607 | biostudies-literature

{N1-[2-(Butyl-selan-yl)benz-yl]-N2,N2-di-methyl-ethane-1,2-di-amine}-dichlorido-mercury(II).

Project description:In the title compound, [HgCl2(C16H28N2Se)], the primary geometry around the Se and Hg atoms is distorted trigonal-pyramidal and distorted square-pyramidal, respectively. The distortion of the mol-ecular geometry in the complex is caused by the steric demands of the ligands attached to the Se atom. The Hg atom is coordinated through two chloride anions, an N atom and an Se atom, making up an unusual HgNSeCl2 coordination sphere with an additional long Hg⋯N inter-action. Inter-molecular C-H⋯Cl inter-actions are the only identified inter-molecular hydrogen-bonding inter-actions that seem to be responsible for the self assembly. These relatively weak C-H⋯Cl hydrogen bonds possess the required linearity and donor-acceptor distances. They act as mol-ecular associative forces that result in a supra-molecular assembly along the b-axis direction in the solid state of the title compound.

| S-EPMC6072982 | biostudies-literature

1,1'-(Ethane-1,2-di-yl)bis-(1,4,7-triazonane).

Project description:In the centrosymmetric title compound (dtne), C(14)H(32)N(6), two 1,4,7-triaza-cyclo-nonane (tacn, or 1,4,7-triazonane) moieties are linked together each at an amino position by a single ethyl-ene spacer. The mol-ecular packing is supported by pairs of inter-molecular N-H?N hydrogen bonds, which form R(2) (2)(22) ring motifs and link the mol-ecules into infinite chains running parallel to the a axis.

| S-EPMC2979561 | biostudies-literature

1,1'-(Ethane-1,2-di-yl)dipyridinium bis-(iodate).

Project description:The title salt, C(12)H(14)N(2) (2+)·2IO(3) (-), exhibits two crystallographically independent iodate anions, the I atoms of which are each in a trigonal-pyramidal environment. In the dication, the two pyridine rings adopt an anti conformation with respect to each other; the angle between these two rings is 3.84 (19)°. In the crystal structure, C-H⋯O hydrogen bonds between the cations and anions lead to the formation of layers arranged parallel to the ab plane. I⋯O halogen bonds [R(2) (2)(4) graph-set motif] range between 2.873 (2) and 3.036 (3) Å and connect neighbouring IO(3) (-) anions with each other along [100], so as to create a three-dimensional network.

| S-EPMC3151914 | biostudies-literature

1,1'-(Ethane-1,2-di-yl)dipyridinium bis-(1,2-di-cyano-ethene-1,2-di-thiol-ato-κ(2) S,S')cuprate(II).

Project description:In the title ion-pair complex, (C12H14N2)[Cu(C4N2S2)2], the complex anion exhibits a highly twisted coordination environment around the tetra-coordinated Cu(II) atom. The dihedral angles between the 1,2-di-cyano-ethene-1,2-di-thiol-ato ligands and between the two pyridine rings in the cation are 37.49 (3) and 29.18 (10)°, respectively. Weak C-H⋯N and C-H⋯S hydrogen bonds link the cations and anions into a three-dimensional network.

| S-EPMC3684877 | biostudies-literature

Di-μ-bromido-bis-({bis-[2-(2-pyrid-yl)eth-yl]amine}copper(II)) bis-(perchlorate).

Project description:Each Cu atom in the dinuclear centrosymmetric title complex, [Cu(2)Br(2)(C(14)H(17)N(3))(2)](ClO(4))(2), is ligated in a distorted square-pyramidal geometry (τ = 0.31) by a tridentate bis-[2-(2-pyrid-yl)eth-yl]amine ligand, and by two bridging Br atoms. In addition, the dinuclear species is stabilized by two hydrogen-bonded perchlorate anions.

| S-EPMC2960247 | biostudies-literature

1,1'-(Ethane-1,2-di-yl)bis-(indoline-2,3-dione).

Project description:The mol-ecule of the title compound, C(18)H(12)N(2)O(4), is situated on a crystallographic centre of symmetry. The mol-ecule has a zigzag structure, with two parallel symmetry-related indoline-2,3-dione fragments linked by an ethyl-ene group at each N atom. In the crystal, the mol-ecules stack in columns along the b axis. There are two such columns in the structure. The mol-ecules within each column are parallel; however, the mol-ecules in the two columns differ in the respective orientation of the indoline-2,3-dione fragments. In one column, they are approximately parallel to (112), while in the other they are approximately parallel to (12). The inter-planar angle between the indoline-2,3-dione fragments in the two columns is 80.83?(3)°. The mol-ecules within each column are related by mutual displacement of their centres of symmetry, that is (0, ±1/2, ±1/2). The packing between the mol-ecules is provided by weak inter-actions only, viz. C-H?O hydrogen bonds and ?-? [centroid-centroid distance = 3.8745?(8)?Å] and C=O?? inter-actions.

| S-EPMC3006689 | biostudies-literature

catena-Poly[[[di-aqua-bis-(seleno-cyanato-κN)iron(II)]-μ-1,2-bis-(pyridin-4-yl)ethane-κ(2) N:N'] 1,2-bis-(pyridin-4-yl)ethane disolvate dihydrate].

Project description:The title compound, {[Fe(NCSe)2(C12H12N2)(H2O)2]·2C12H12N2·2H2O} n , was obtained by the reaction of iron(II) sulfate hepta-hydrate and potassium seleno-cyanate with 1,2-bis-(pyridin-4-yl)ethane (bpa) in water. The Fe(II) cation is coordinated by two N-bonded seleno-cyanate anions, two water mol-ecules and two 1,2-bis-(pyridin-4-yl)ethane (bpa) ligands in a slightly distorted octa-hedral geometry. In addition, two non-coordinating bpa mol-ecules and two water mol-ecules are present. The Fe(II) cation is located on a center of inversion while the coordinating bpa ligand is located on a twofold rotation axis. The Fe(II) cations are linked by the bpa ligands into chains along the b-axis direction, which are further connected into layers perpedicular to the c axis by O-H⋯N and O-H⋯O hydrogen bonds to the non-coordin-ating bpa and the water mol-ecules. The crystal studied was twinned by pseudo-merohedry (180° rotation along c*; contribution of the minor twin component 3.7%).

| S-EPMC3684883 | biostudies-literature

[N,N'-(1,2-Diphenyl-ethane-1,2-di-yl)bis-(pyridine-2-carboxamidato)]nickel(II) diethyl ether hemisolvate.

Project description:In the title compound, [Ni(C(26)H(20)N(4)O(2))]·0.5C(4)H(10)O, the central metal ion is coordinated by four atoms of the tetra-dentate picolinamide ligand, forming a slightly distorted square-planar configuration, with an average Ni-N(pyridine) distance of 1.94?Å and an average Ni-N(amide) distance of 1.83?Å. The asymmetric unit contains one half-molecule of diethyl ether; this solvent molecule is disordered across a twofold rotation axis..

| S-EPMC2960759 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data