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Trimethyl-phenyl-ammonium ?-bromido-bis-[dibromidobis(4-bromobenzyl)stannate(IV)].

ABSTRACT: In the title salt, [C(6)H(5)N(CH(3))(3)][Sn(2)Br(5)(C(7)H(6)Br)(4)], the Sn(IV) atoms of the dinuclear anion are bridged by a Br atom; the Sn-Br(bridge) bond lengths are 2.9818?(5) and 3.0470?(5)?Å. Both Sn atoms show a distorted cis-trigonal-bipyramidal coordination geometry that is distorted towards a square pyramid. In the crystal, weak C-H?? inter-actions occur between anions and cations.

SUBMITTER: Keng TC

PROVIDER: S-EPMC3151895 | biostudies-other | 2011 Jul

REPOSITORIES: biostudies-other

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Trimethyl-phenyl-ammonium μ-bromido-bis-[dibromidobis(4-bromobenzyl)stannate(IV)].

Keng Thy Chun TC Lo Kong Mun KM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20110611 Pt 7

In the title salt, [C(6)H(5)N(CH(3))(3)][Sn(2)Br(5)(C(7)H(6)Br)(4)], the Sn(IV) atoms of the dinuclear anion are bridged by a Br atom; the Sn-Br(bridge) bond lengths are 2.9818 (5) and 3.0470 (5) Å. Both Sn atoms show a distorted cis-trigonal-bipyramidal coordination geometry that is distorted towards a square pyramid. In the crystal, weak C-H⋯π inter-actions occur between anions and cations. ...[more]

PMID: 21836868

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