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(7R,8S,9S,12S)-1-(4-Chloro-benz-yloxy)-13,14-didehydro-12-hy-droxy-2,13-dimeth-oxy-N-methyl-morphinane.

ABSTRACT: The title compound, C(26)H(30)ClNO(4), a sinomenine derivative, has five six-membered rings, two of which are aromatic, with a dihedral angle of 34.13?(20)° between these. The N-containing ring and the fourth ring exhibit chair conformations, while the fifth ring approximates an envelope conformation. A single inter-molecular O-H?N hydrogen-bonding inter-action gives a one-dimensional chain structure which extends along the a axis. The absolute configuration for the mol-ecule has been determined.

SUBMITTER: Zheng XL 

PROVIDER: S-EPMC3200812 | biostudies-other | 2011 Sep

REPOSITORIES: biostudies-other

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(7R,8S,9S,12S)-1-(4-Chloro-benz-yloxy)-13,14-didehydro-12-hy-droxy-2,13-dimeth-oxy-N-methyl-morphinane.

Zheng Xing-Liang XL   Jiang Ning-Fei NF   Gao Hong-Sheng HS   Luo Dan D   Ding Ai-Shun AS  

Acta crystallographica. Section E, Structure reports online 20110827 Pt 9

The title compound, C(26)H(30)ClNO(4), a sinomenine derivative, has five six-membered rings, two of which are aromatic, with a dihedral angle of 34.13 (20)° between these. The N-containing ring and the fourth ring exhibit chair conformations, while the fifth ring approximates an envelope conformation. A single inter-molecular O-H⋯N hydrogen-bonding inter-action gives a one-dimensional chain structure which extends along the a axis. The absolute configuration for the mol-ecule has been determined  ...[more]

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