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8-Hy-droxy-2-methyl-quinolinium dibromido(2-methyl-quinolin-8-olato-?N,O)zincate acetonitrile mono-solvate.

ABSTRACT: The reaction of 2-methyl-8-hy-droxy-quinoline and zinc bromide in acetonitrile affords the title solvated salt, (C(10)H(10)NO)[ZnBr(2)(C(10)H(8)NO)]·CH(3)CN, in which the Zn(II) ion is coordinated by a N,O-chelating 2-methyl-quinolin-8-olate ligand and two bromide ligands in a distorted tetra-hedral geometry. The cation is linked to the anion by an O-H?O hydrogen bond and the quinolinium H atom forms an inter-molecular N-H?N hydrogen bond with the acetonitrile solvent mol-ecule.

SUBMITTER: Najafi E

PROVIDER: S-EPMC3200891 | biostudies-other | 2011 Sep

REPOSITORIES: biostudies-other

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8-Hy-droxy-2-methyl-quinolinium dibromido(2-methyl-quinolin-8-olato-κN,O)zincate acetonitrile mono-solvate.

Najafi Ezzatollah E Amini Mostafa M MM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20110827 Pt 9

The reaction of 2-methyl-8-hy-droxy-quinoline and zinc bromide in acetonitrile affords the title solvated salt, (C(10)H(10)NO)[ZnBr(2)(C(10)H(8)NO)]·CH(3)CN, in which the Zn(II) ion is coordinated by a N,O-chelating 2-methyl-quinolin-8-olate ligand and two bromide ligands in a distorted tetra-hedral geometry. The cation is linked to the anion by an O-H⋯O hydrogen bond and the quinolinium H atom forms an inter-molecular N-H⋯N hydrogen bond with the acetonitrile solvent mol-ecule. ...[more]

PMID: 22058877

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A potential anti-cancer agent: 5-chloro-7-iodo-8-hy-droxy-quinolinium dichlorido(5-chloro-7-iodo-quinolin-8-olato-κN,O)palladium(II) dihydrate.

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