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8-Hydr-oxy-2-methyl-quinolinium tetra-chlorido(quinolin-8-olato-?N,O)stannate(IV) acetonitrile monosolvate.


ABSTRACT: In the title solvated salt, (C(10)H(10)NO)[SnCl(4)(C(9)H(6)NO)]·CH(3)CN, the Sn(IV) atom is chelated by the N,O-bidentate 8-hydroxy-quinolinate ligand and four chloride ions, generating a distorted SnONCl(4) octa-hedral coordination geometry for the metal. In the crystal, the cations are linked to the anions and the solvent mol-ecules by O-H?O and N-H?N hydrogen bonds, respectively.

SUBMITTER: Vafaee M 

PROVIDER: S-EPMC2983816 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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8-Hydr-oxy-2-methyl-quinolinium tetra-chlorido(quinolin-8-olato-κN,O)stannate(IV) acetonitrile monosolvate.

Vafaee Marzieh M   Mohammadnezhad Gholamhossein G   Amini Mostafa M MM   Ng Seik Weng SW  

Acta crystallographica. Section E, Structure reports online 20100306 Pt 4


In the title solvated salt, (C(10)H(10)NO)[SnCl(4)(C(9)H(6)NO)]·CH(3)CN, the Sn(IV) atom is chelated by the N,O-bidentate 8-hydroxy-quinolinate ligand and four chloride ions, generating a distorted SnONCl(4) octa-hedral coordination geometry for the metal. In the crystal, the cations are linked to the anions and the solvent mol-ecules by O-H⋯O and N-H⋯N hydrogen bonds, respectively. ...[more]

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