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Tetra-carbon-yl[bis-(diphenyl-phosphan-yl)tetra-methyl-disiloxane-?P,P']chromium(0).

ABSTRACT: The title compound, [Cr(C(28)H(32)OP(2)Si(2))(CO)(4)], was obtained by the ligand-exchange reaction of Cr(CO)(6) with (Ph(2)PSiMe(2))(2)O in refluxing toluene. The CrC(4)P(2) coordination geometry is distorted octa-hedral, with a P-Cr-P bite angle of 99.22?(4)°.

SUBMITTER: Peulecke N

PROVIDER: S-EPMC3274860 | biostudies-other | 2012 Feb

REPOSITORIES: biostudies-other

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Tetra-carbon-yl[bis-(diphenyl-phosphan-yl)tetra-methyl-disiloxane-κP,P']chromium(0).

Peulecke Normen N Müller Bernd H BH Spannenberg Anke A Rosenthal Uwe U

Acta crystallographica. Section E, Structure reports online 20120107 Pt 2

The title compound, [Cr(C(28)H(32)OP(2)Si(2))(CO)(4)], was obtained by the ligand-exchange reaction of Cr(CO)(6) with (Ph(2)PSiMe(2))(2)O in refluxing toluene. The CrC(4)P(2) coordination geometry is distorted octa-hedral, with a P-Cr-P bite angle of 99.22 (4)°. ...[more]

PMID: 22346807

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