Unknown

Dataset Information

0

[Bis(diphenyl-phosphan-yl)dimethyl-silane-?P,P']tetra-carbonyl-chromium(0).


ABSTRACT: The title compound, [Cr(C(26)H(26)P(2)Si)(CO)(4)], was obtained by the reaction of Ph(2)PSiMe(2)PPh(2) with Cr(CO)(6) in refluxing toluene by ligand exchange. The CrC(4)P(2) coordination geometry at the Cr atom is distorted octa-hedral, with a P-Cr-P bite angle of 80.27?(1)°.

SUBMITTER: Peulecke N 

PROVIDER: S-EPMC3009008 | biostudies-other | 2010

REPOSITORIES: biostudies-other

altmetric image

Publications

[Bis(diphenyl-phosphan-yl)dimethyl-silane-κP,P']tetra-carbonyl-chromium(0).

Peulecke Normen N   Peitz Stephan S   Müller Bernd H BH   Spannenberg Anke A   Rosenthal Uwe U  

Acta crystallographica. Section E, Structure reports online 20101031 Pt 11


The title compound, [Cr(C(26)H(26)P(2)Si)(CO)(4)], was obtained by the reaction of Ph(2)PSiMe(2)PPh(2) with Cr(CO)(6) in refluxing toluene by ligand exchange. The CrC(4)P(2) coordination geometry at the Cr atom is distorted octa-hedral, with a P-Cr-P bite angle of 80.27 (1)°. ...[more]

Similar Datasets

| S-EPMC3009317 | biostudies-literature
| S-EPMC3200751 | biostudies-literature
| S-EPMC3274860 | biostudies-other
| S-EPMC2968563 | biostudies-literature
| S-EPMC3238589 | biostudies-literature
| S-EPMC3200925 | biostudies-literature
| S-EPMC3393151 | biostudies-literature
| S-EPMC3393193 | biostudies-literature
| S-EPMC2971763 | biostudies-literature
| S-EPMC3201522 | biostudies-literature