Ontology highlight
ABSTRACT:
SUBMITTER: Peulecke N
PROVIDER: S-EPMC3009008 | biostudies-other | 2010
REPOSITORIES: biostudies-other
Peulecke Normen N Peitz Stephan S Müller Bernd H BH Spannenberg Anke A Rosenthal Uwe U
Acta crystallographica. Section E, Structure reports online 20101031 Pt 11
The title compound, [Cr(C(26)H(26)P(2)Si)(CO)(4)], was obtained by the reaction of Ph(2)PSiMe(2)PPh(2) with Cr(CO)(6) in refluxing toluene by ligand exchange. The CrC(4)P(2) coordination geometry at the Cr atom is distorted octa-hedral, with a P-Cr-P bite angle of 80.27 (1)°. ...[more]