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[Bis(diphenyl-phosphan-yl)dimethyl-silane-?P,P']tetra-carbonyl-chromium(0).

ABSTRACT: The title compound, [Cr(C(26)H(26)P(2)Si)(CO)(4)], was obtained by the reaction of Ph(2)PSiMe(2)PPh(2) with Cr(CO)(6) in refluxing toluene by ligand exchange. The CrC(4)P(2) coordination geometry at the Cr atom is distorted octa-hedral, with a P-Cr-P bite angle of 80.27?(1)°.

SUBMITTER: Peulecke N

PROVIDER: S-EPMC3009008 | biostudies-other | 2010

REPOSITORIES: biostudies-other

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[Bis(diphenyl-phosphan-yl)dimethyl-silane-κP,P']tetra-carbonyl-chromium(0).

Peulecke Normen N Peitz Stephan S Müller Bernd H BH Spannenberg Anke A Rosenthal Uwe U

Acta crystallographica. Section E, Structure reports online 20101031 Pt 11

The title compound, [Cr(C(26)H(26)P(2)Si)(CO)(4)], was obtained by the reaction of Ph(2)PSiMe(2)PPh(2) with Cr(CO)(6) in refluxing toluene by ligand exchange. The CrC(4)P(2) coordination geometry at the Cr atom is distorted octa-hedral, with a P-Cr-P bite angle of 80.27 (1)°. ...[more]

PMID: 21588907

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