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[2,2-Bis(diphenyl-phosphan-yl)propane-?P,P']tetra-carbonyl-chromium(0) dichloro-methane monosolvate.

ABSTRACT: The title compound, [Cr(C(27)H(26)P(2))(CO)(4)]·CH(2)Cl(2), was obtained by the reaction of Ph(2)PCMe(2)PPh(2) with Cr(CO)(6) in refluxing toluene by substitution of two carbonyl ligands. The CrC(4)P(2) coordination geometry at the Cr atom is distorted octa-hedral, with a P-Cr-P bite angle of 70.27?(2)°.

SUBMITTER: Peulecke N

PROVIDER: S-EPMC3009317 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature

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[2,2-Bis(diphenyl-phosphan-yl)propane-κP,P']tetra-carbonyl-chromium(0) dichloro-methane monosolvate.

Peulecke Normen N Peitz Stephan S Müller Bernd H BH Spannenberg Anke A Rosenthal Uwe U

Acta crystallographica. Section E, Structure reports online 20101031 Pt 11

The title compound, [Cr(C(27)H(26)P(2))(CO)(4)]·CH(2)Cl(2), was obtained by the reaction of Ph(2)PCMe(2)PPh(2) with Cr(CO)(6) in refluxing toluene by substitution of two carbonyl ligands. The CrC(4)P(2) coordination geometry at the Cr atom is distorted octa-hedral, with a P-Cr-P bite angle of 70.27 (2)°. ...[more]

PMID: 21588908

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