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ABSTRACT:
SUBMITTER: Peulecke N
PROVIDER: S-EPMC3009317 | biostudies-literature | 2010 Oct
REPOSITORIES: biostudies-literature
Peulecke Normen N Peitz Stephan S Müller Bernd H BH Spannenberg Anke A Rosenthal Uwe U
Acta crystallographica. Section E, Structure reports online 20101031 Pt 11
The title compound, [Cr(C(27)H(26)P(2))(CO)(4)]·CH(2)Cl(2), was obtained by the reaction of Ph(2)PCMe(2)PPh(2) with Cr(CO)(6) in refluxing toluene by substitution of two carbonyl ligands. The CrC(4)P(2) coordination geometry at the Cr atom is distorted octa-hedral, with a P-Cr-P bite angle of 70.27 (2)°. ...[more]