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Di-?-chlorido-bis-{bis-[4-(adamantan-1-ylcarbamo-yl)pyridine-?N]chlorido-copper(II)} hemihydrate.

ABSTRACT: In the centrosymmetric dimeric title compound, [Cu(2)Cl(4)(C(16)H(20)N(2)O)(4)]·0.5H(2)O, the Cu(II) atom is in a distorted trigonal-bipyramidal environment defined by two bridging Cl atoms, one terminal Cl atom and two N atoms from two monodentate 4-(adamantan-1-ylcarbamo-yl)pyridine ligands. The amine N atoms are involved in intra-molecular N-H?O and inter-molecular N-H?Cl hydrogen bonds. The latter hydrogen bonds link the complex mol-ecules into a ribbon along [010]. The uncoordinated water mol-ecule is 0.25-occupied.

SUBMITTER: Wang YC

PROVIDER: S-EPMC3274881 | biostudies-other | 2012 Feb

REPOSITORIES: biostudies-other

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Di-μ-chlorido-bis-{bis-[4-(adamantan-1-ylcarbamo-yl)pyridine-κN]chlorido-copper(II)} hemihydrate.

Wang Ying-Chun YC

Acta crystallographica. Section E, Structure reports online 20120114 Pt 2

In the centrosymmetric dimeric title compound, [Cu(2)Cl(4)(C(16)H(20)N(2)O)(4)]·0.5H(2)O, the Cu(II) atom is in a distorted trigonal-bipyramidal environment defined by two bridging Cl atoms, one terminal Cl atom and two N atoms from two monodentate 4-(adamantan-1-ylcarbamo-yl)pyridine ligands. The amine N atoms are involved in intra-molecular N-H⋯O and inter-molecular N-H⋯Cl hydrogen bonds. The latter hydrogen bonds link the complex mol-ecules into a ribbon along [010]. The uncoordinated water m ...[more]

PMID: 22346828

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