Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

4-(Dimethyl-amino)-pyridinium tetra-chlorido(pyridine-2-carboxyl-ato-?(2)N,O)stannate(IV).

ABSTRACT: The reaction of 4-(dimethyl-amino)-pyridine, picolinic acid and stannic chloride yields the title salt, (C(7)H(11)N(2))[SnCl(4)(C(6)H(4)NO(2))], in which the Sn(IV) atom is N,O-chelated by the picolinate ion in a cis-SnNOCl(4) octa-hedral geometry. The cation is linked to the anion by an N-H?O hydrogen bond.

SUBMITTER: Najafi E

PROVIDER: S-EPMC3379084 | biostudies-other | 2012 Jun

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Publications

4-(Dimethyl-amino)-pyridinium tetra-chlorido(pyridine-2-carboxyl-ato-κ(2)N,O)stannate(IV).

Najafi Ezzatollah E Amini Mostafa M MM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20120505 Pt 6

The reaction of 4-(dimethyl-amino)-pyridine, picolinic acid and stannic chloride yields the title salt, (C(7)H(11)N(2))[SnCl(4)(C(6)H(4)NO(2))], in which the Sn(IV) atom is N,O-chelated by the picolinate ion in a cis-SnNOCl(4) octa-hedral geometry. The cation is linked to the anion by an N-H⋯O hydrogen bond. ...[more]

PMID: 22719305

Similar Datasets

2-Meth-oxy-carbonyl-pyridinium tetra-chlorido(pyridine-2-carboxyl-ato-κN,O)stannate(IV).

Project description:In the reaction of pyridine-2-carb-oxy-lic acid and stannic chloride in methanol, one equivalent of the carb-oxy-lic acid is protonated at the amino site and is also esterified, yielding the title salt, (C(7)H(8)NO(2))[SnCl(4)(C(6)H(4)NO(2))]. The Sn(IV) atom in the anion is N,O-chelated by a pyridine-2-carboxyl-ate in a cis-SnNOCl(4) octa-hedral geometry. The cation is linked to the anion by an N-H⋯O hydrogen bond.

| S-EPMC3051751 | biostudies-literature

4-(Dimethyl-amino)-pyridinium tetra-chlorido(quinoline-2-carboxyl-ato-?N,O)stannate(IV).

Project description:In the title salt, (C(7)H(11)N(2))[SnCl(4)(C(10)H(6)NO(2))], the Sn(IV) atom is chelated by the N,O-bidentate carboxyl-ate ions and four chloride ions, showing a distorted octa-hedral SnNOCl(4) coordination. In the crystal, the cation and anion are linked by a pyridinium-carboxyl-ate N-H?O hydrogen bond.

| S-EPMC3200806 | biostudies-other

Triethyl-ammonium tetra-chlorido(pyridine-2-carboxyl-ato-κN,O)stannate(IV).

Project description:The cation and the anion in the title salt, (C(6)H(16)N)[SnCl(4)(C(6)H(4)NO(2))], are linked by an N-H⋯O hydrogen bond. The Sn(IV) atom in the stannate anion is chelated by the pyridine-2-carboxyl-ate group and exists in a cis-SnCl(4)NO octa-hedral geometry. The cation is disordered over two positions in a 0.564 (1):0.436 (1) ratio.

| S-EPMC3052166 | biostudies-literature

8-Hy-droxy-2-methyl-quinolinium tetra-chlorido(pyridine-2-carboxyl-ato-κN,O)stannate(IV).

Project description:In the reaction of pyridine-2-carb-oxy-lic acid and stannic chloride in the presence of 2-methyl-8-hy-droxy-quinoline, the 2-methyl-8-hy-droxy-quinoline is protonated, yielding the title salt, (C(10)H(10)NO)[SnCl(4)(C(6)H(4)NO(2))]. The Sn(IV) atom in the anion is N,O-chelated by a pyridine-2-carboxyl-ate in a cis-SnNOCl(4) octa-hedral geometry. The cation is linked to the anion by an O-H⋯O hydrogen bond.

| S-EPMC3051689 | biostudies-literature

Bis[4-(dimethyl-amino)pyridinium] tetra-bromidodiphenyl-stannate(IV).

Project description:The Sn(IV) atom of the stannate anion in the title salt, (C(7)H(11)N(2))(2)[SnBr(4)(C(6)H(5))(2)], lies on a center of inversion in a tetra-gonally compressed octa-hedron. The two independent Br atoms in the anion are hydrogen-bond acceptors for the same cation.

| S-EPMC2961153 | biostudies-literature

Triethyl-ammonium tetra-chlorido(pyrazine-2-carboxyl-ato-?N,O)stannate(IV).

Project description:The Sn(IV) atom in the title ammonium stannate, (Et(3)NH)[Sn(C(5)H(3)N(2)O(2))Cl(4)], is chelated by an pyrazine-2-carboxyl-ate ligand and exists in a cis-SnCl(4)NO octa-hedral geometry. The cation and the anion are linked by an N-H?N hydrogen bond.

| S-EPMC3120576 | biostudies-literature

Bis[4-(dimethyl-amino)pyridinium] hexa-kis[bromido/chlorido(0.78/0.22)]stannate(IV).

Project description:The Sn atom in the title salt, (C(7)H(11)N(2))(2)[SnBr(4.67)Cl(1.33)], lies on a center of symmetry within an octa-hedron of disordered halogen atoms. The three independent halogen atoms are each a mixture of bromine and chlorine atoms [with site occupancies for bromine of 0.614?(1), 0.831?(1) and 0.888?(1)]. An N-H? hydrogen bond is present.

| S-EPMC2969252 | biostudies-literature

Bis[4-(dimethyl-amino)pyridinium] tetra-bromidobis(4-methyl-phen-yl)stannate(IV).

Project description:In the title compound, (C(7)H(11)N(2))(2)[SnBr(4)(C(7)H(7))(2)], the tetra-bromidobis(4-methyl-phen-yl)stannate(IV) anion possesses a centre of inversion located at the Sn(IV) atom. In the crystal structure, two inversion-related cations are linked to the anion via weak N-H⋯Br hydrogen bonds.

| S-EPMC2970024 | biostudies-literature

Bis[4-(dimethyl-amino)-pyridinium] dibromidodichloridodimethyl-stannate(IV).

Project description:The tin(IV) atom in the salt, (C(7)H(11)N(2))(2)[SnBr(2)(CH(3))(2)Cl(2)], lies on a center of inversion in a tetra-gonally compressed octa-hedron; the bromine atoms are disordered with the chlorine atoms, so that they appear to share the same site. The crystal structure is stabilized by N-H?Br hydrogen bonds.

| S-EPMC2961524 | biostudies-literature

Bis[4-(dimethyl-amino)pyridinium] tribromidochloridodimethyl-stannate(IV).

Project description:The Sn(IV) atom in the title salt, (C(7)H(11)N(2))(2)[SnBr(3)(CH(3))(2)Cl], lies on a center of inversion in a tetra-gonally compressed octa-hedron; two independent Br atoms share the same site as two independent chlorine atoms so that the anion effectively has one Cl and three Br atoms. The occupancies of the Br atoms are 0.721 (1) and 0.779 (1), and those of the Cl atoms are 0.279 (1) and 0.221 (1). The crystal structure involves N-H⋯halogen hydrogen bonds.

| S-EPMC2961353 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data