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4-(Dimethyl-amino)-pyridinium tetra-chlorido(pyridine-2-carboxyl-ato-?(2)N,O)stannate(IV).

ABSTRACT: The reaction of 4-(dimethyl-amino)-pyridine, picolinic acid and stannic chloride yields the title salt, (C(7)H(11)N(2))[SnCl(4)(C(6)H(4)NO(2))], in which the Sn(IV) atom is N,O-chelated by the picolinate ion in a cis-SnNOCl(4) octa-hedral geometry. The cation is linked to the anion by an N-H?O hydrogen bond.

SUBMITTER: Najafi E

PROVIDER: S-EPMC3379084 | biostudies-other | 2012 Jun

REPOSITORIES: biostudies-other

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4-(Dimethyl-amino)-pyridinium tetra-chlorido(pyridine-2-carboxyl-ato-κ(2)N,O)stannate(IV).

Najafi Ezzatollah E Amini Mostafa M MM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20120505 Pt 6

The reaction of 4-(dimethyl-amino)-pyridine, picolinic acid and stannic chloride yields the title salt, (C(7)H(11)N(2))[SnCl(4)(C(6)H(4)NO(2))], in which the Sn(IV) atom is N,O-chelated by the picolinate ion in a cis-SnNOCl(4) octa-hedral geometry. The cation is linked to the anion by an N-H⋯O hydrogen bond. ...[more]

PMID: 22719305

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