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Tetra-phenyl-phospho-nium [?3-(4-methyl-phen-yl)tellurolato]tris-[tetra-carbonyl-iron(0)].

ABSTRACT: In the anion of the title compound, (C24H20P)[Fe3(C7H7Te)(CO)12], each Fe(0) atom is coordinated by four CO ligands and a Te atom, resulting in a trigonal-bipyramidal coordination environment. The Te atom is coordinated by a 4-methyl-phenyl group and the Fe(0) atoms in a distorted tetra-hedral geometry. The average Te-Fe bond length is 2.574?(4)?Å.

SUBMITTER: Li YL

PROVIDER: S-EPMC3684888 | biostudies-other | 2013 Jun

REPOSITORIES: biostudies-other

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Tetra-phenyl-phospho-nium [μ3-(4-methyl-phen-yl)tellurolato]tris-[tetra-carbonyl-iron(0)].

Li Yu-Long YL Xie Bin B Zou Li-Ke LK

Acta crystallographica. Section E, Structure reports online 20130518 Pt 6

In the anion of the title compound, (C24H20P)[Fe3(C7H7Te)(CO)12], each Fe(0) atom is coordinated by four CO ligands and a Te atom, resulting in a trigonal-bipyramidal coordination environment. The Te atom is coordinated by a 4-methyl-phenyl group and the Fe(0) atoms in a distorted tetra-hedral geometry. The average Te-Fe bond length is 2.574 (4) Å. ...[more]

PMID: 23794990

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