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Bis(2-meth-oxy-anilinium) hexa-bromido-stannate(IV) dihydrate.

ABSTRACT: The asymmetric unit of the title compound, (C7H10NO)2[SnBr6]·2H2O, contains one cation, one half-dianion and one lattice water mol-ecule. The [SnBr6](2-) dianion, located on an inversion center, exhibits a highly distorted octa-hedral coordination environment, with Sn-Br bond lengths ranging from 2.2426?(9) to 3.0886?(13)?Å. In the crystal, O-H?Br, N-H?Br, N-H?O and C-H?Br hydrogen bonds consolidate the packing, which can be described as consisting of alternating anionic (containing dianions and lattice water mol-ecules) and cationic layers parallel to ab plane.

SUBMITTER: Chouaib H 

PROVIDER: S-EPMC3885007 | biostudies-other | 2013 Nov

REPOSITORIES: biostudies-other

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Bis(2-meth-oxy-anilinium) hexa-bromido-stannate(IV) dihydrate.

Chouaib Hassen H   Karoui Sahel S   Kamoun Slaheddine S   Michaud Francois F  

Acta crystallographica. Section E, Structure reports online 20131123 Pt 12

The asymmetric unit of the title compound, (C7H10NO)2[SnBr6]·2H2O, contains one cation, one half-dianion and one lattice water mol-ecule. The [SnBr6](2-) dianion, located on an inversion center, exhibits a highly distorted octa-hedral coordination environment, with Sn-Br bond lengths ranging from 2.2426 (9) to 3.0886 (13) Å. In the crystal, O-H⋯Br, N-H⋯Br, N-H⋯O and C-H⋯Br hydrogen bonds consolidate the packing, which can be described as consisting of alternating anionic (containing dianions and  ...[more]

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