Ontology highlight
ABSTRACT:
SUBMITTER: Jans AC
PROVIDER: S-EPMC5053284 | biostudies-other | 2016 Oct
REPOSITORIES: biostudies-other
Chemistry (Weinheim an der Bergstrasse, Germany) 20160904 42
Dinuclear gold complexes have the ability to interact with one or more substrates in a dual-activation mode, leading to different reactivity and selectivity than their mononuclear relatives. In this contribution, this difference was used to control the catalytic properties of a gold-based catalytic system by site-isolation of mononuclear gold complexes by selective encapsulation. The typical dual-activation mode is prohibited by this catalyst encapsulation, leading to typical behavior as a resul ...[more]