Ontology highlight
ABSTRACT:
SUBMITTER: Roth T
PROVIDER: S-EPMC5647813 | biostudies-other | 2015 Apr
REPOSITORIES: biostudies-other
Roth Torsten T Vasilenko Vladislav V Benson Callum G M CGM Wadepohl Hubert H Wright Dominic S DS Gade Lutz H LH
Chemical science 20150213 4
A simple, "click" synthetic approach to a new type of hybrid phosph(III)azane/NHC system is described. The presence of the phosphazane P<sub>2</sub>N<sub>2</sub> ring unit, with P atoms flanking the <i>NCN</i> fragment and with this ring perpendicular to the binding site of the NHC, provides unique opportunities for modifying the electronic and steric character of these carbenes. ...[more]