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Trans-Carbon-yl[dihydro-bis(1,2,4-triazol-1-yl-?N)borato]hydridobis(triphenyl-phosphine-?P)ruthenium(II) acetonitrile solvate.

ABSTRACT: In the crystal structure of the title compound, [Ru(C(4)H(6)BN(6))H(C(18)H(15)P)(2)(CO)]·C(2)H(3)N, discrete mononuclear complexes are found in which the Ru atom is coordinated by two triphenyl-phosphine (PPh(3)) ligands, one dihydro-bis(1,2,4-triazol-1-yl)borate ligand, one carbonyl ligand and one hydride atom within slightly distorted octa-hedra. The two P atoms of the PPh(3) ligands are trans positioned and the two N atoms of the chelating dihydro-bis(1,2,4-triazol-1-yl)borate ligand occupy cis positions.

SUBMITTER: Huh S

PROVIDER: S-EPMC2960167 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

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trans-Carbon-yl[dihydro-bis(1,2,4-triazol-1-yl-κN)borato]hydridobis(triphenyl-phosphine-κP)ruthenium(II) acetonitrile solvate.

Huh Seong S

Acta crystallographica. Section E, Structure reports online 20080104 Pt 2

In the crystal structure of the title compound, [Ru(C(4)H(6)BN(6))H(C(18)H(15)P)(2)(CO)]·C(2)H(3)N, discrete mononuclear complexes are found in which the Ru atom is coordinated by two triphenyl-phosphine (PPh(3)) ligands, one dihydro-bis(1,2,4-triazol-1-yl)borate ligand, one carbonyl ligand and one hydride atom within slightly distorted octa-hedra. The two P atoms of the PPh(3) ligands are trans positioned and the two N atoms of the chelating dihydro-bis(1,2,4-triazol-1-yl)borate ligand occupy c ...[more]

PMID: 21201268

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