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Azido-(1,1-diphenyl-methanimine-κN)[hydridotris(pyrazolyl-κN)borato](triphenyl-phosphine-κP)ruthenium(II) diethyl ether solvate.

ABSTRACT: The reaction of [RuCl(C(9)H(10)BN(6))(C(18)H(15)P)(2)] with benzo-phenone imine in methanol, in the presence of sodium azide, leads to the formation of the title compound, [Ru(C(9)H(10)BN(6))(N(3))(HN=CPh(2))(C(18)H(15)P)]·C(4)H(10)O, which crystallizes as the diethyl ether solvate. In the crystal structure, the Ru atom is coordinated by three N atoms of one hydridotris(pyrazoly)borate anion, one P atom of one triphenyl-phosphine ligand, one N atom of the azide anion and one N atom of the benzophenone-imine ligand in a slightly distorted octa-hedral geometry. The azide anion is almost linear [177.0 (5)°], with an Ru-N-N angle of 125.9 (3)°. There is a small difference between the N-N distances [1.200 (5) and 1.164 (5) Å], the longer bond being adjacent to the Ru atom.

SUBMITTER: Lin CH

PROVIDER: S-EPMC2960095 | biostudies-literature |

REPOSITORIES: biostudies-literature

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(Dithio-benzoato-κS,S')[hydridotris(pyrazol-1-yl-κN)borato](triphenyl-phosphine-κP)ruthenium(II).

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| S-EPMC3515116 | biostudies-literature

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| S-EPMC3515107 | biostudies-literature

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Project description:The phosphine-coordinated Ag(I) atom in the title compound, [Ag(C(21)H(17)BN(6))(C(18)H(15)P)], is also N,N',N''-chelated by the tris-(indazol-yl)borate anion. The resultant N(3)P coordination geometry is tetra-hedral.

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(Benzophenone imine-κN)-chlorido(hydrido-tripyrazolyl-borato)-(triphenyl-phosphine)ruthenium(II) diethyl ether solvate.

Project description:The reaction of RuCl(Tp)(Ph(3)P)(2), where Tp is [(CH)(3)N(2)](3)BH, with benzophenone imine leads to the formation of the title compound, [Ru(C(9)H(10)BN(6))Cl(C(13)H(11)N)(C(18)H(15)P)]·C(4)H(10)O. The environment about the Ru atom corresponds to a slightly distorted octa-hedron and the bite angle of the Tp ligand produces an average N-Ru-N angle of 86.3 (9)°. The three Ru-N(Tp) bond lengths [2.117 (2), 2.079 (2) and 2.084 (2) Å] are slightly longer than the average distance (2.038 Å) in other ruthenium-Tp complexes.

| S-EPMC2959639 | biostudies-literature

Bis(pyridine-κN)bis-(triphenyl-phosphine-κP)copper(I) tetra-fluoridoborate.

Project description:The title compound, [Cu(C(5)H(5)N)(2)(C(18)H(15)P)(2)]BF(4), crystallizes as discrete [(PPh(3))(2)(py)(2)Cu](+) cations and [BF(4)](-) anions and is isostructural with the analogous perchlorate salt. The anion is located in close proximity to the pyridine ligands with weak C-H⋯F inter-actions apparent. The P(2)CuN(2) coordination geometry is pseudo-tetra-hedral, with P-Cu-P and N-Cu-N angles of 116.02 (6) and 101.5 (2)°, respectively.

| S-EPMC2961139 | biostudies-literature

(1,10-Phenanthroline-κN,N')(triphenyl-phosphine-κP)silver(I) trifluoro-methane-sulfonate.

Project description:The structure of the title complex, [Ag(C(12)H(8)N(2))(C(18)H(15)P)]CF(3)SO(3), is based on a distorted trigonal-planar N(2)P coordination of the Ag(I) ion, provided by two N atoms of the bidentate phenanthroline ligand and one P atom of the triphenyl-phosphine ligand. The phenanthroline ligand and one phenyl ring of the triphenyl-phosphine ligand almost lie in one plane (maximum deviation = 0.014 Å from the best planes). The crystal structure may be stabilized by an inter-molecular C-H⋯O hydrogen bond between the phenanthroline ligand and the O atom of the trifluoro-methane-sulfonate anion.

| S-EPMC2969938 | biostudies-literature

Chlorido[hydridotris(pyrazol-1-yl-?N)borato](1H-pyrazole-?N)(triphenyl-phosphine-?P)ruthenium(II).

Project description:In the title compound, [Ru(C(9)H(10)BN(6))Cl(C(3)H(4)N(2))(C(18)H(15)P)], the Ru(II) atom is coordinated by an N,N',N''-tridentate hydrido-trispyrazolylborate (Tp) ligand, a pyrazole (HPz) mol-ecule, a chloride ion and a triphenyl-phosphine ligand, resulting in a distorted RuClPN(4) octa-hedral coordination for the metal ion: the tridentate N atoms occupy one octa-hedral face and the Cl and P atoms are cis. One of the phenyl rings is disordered over two orientations in a 0.547?(10):0.453?(10) ratio, and a weak intra-molecular N-H?Cl hydrogen bond generates an S(5) ring.

| S-EPMC3006890 | biostudies-other

cis-cis-trans-Bis(acetonitrile-κN)dichloridobis(triphenyl-phosphine-κP)ruthenium(II) acetonitrile disolvate.

Project description:The title compound, [RuCl(2)(C(2)H(3)N)(2)(C(18)H(15)P)(2)]·2C(2)H(3)N, was obtained upon stirring an acetonitrile/ethanol solution of [RuCl(2)(PPh(3))(3)]. In the crystal structure, each Ru(II) ion is coordinated by two Cl [Ru-Cl = 2.4308 (7) and 2.4139 (7) Å], two N [Ru-N = 2.016 (2) and 2.003 (2) Å], and two P [Ru-P = 2.3688 (7) and 2.3887 (7) Å] atoms in a distorted octa-hedral geometry. Packing inter-actions include typical C-H⋯π contacts involving phenyl groups as well as weak hydrogen bonds between CH(3)CN methyl H atoms and Cl or solvent CH(3)CN N atoms.

| S-EPMC2915117 | biostudies-literature

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