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(Dithio-benzoato-?S,S')[hydridotris(pyrazol-1-yl-?N)borato](triphenyl-phosphine-?P)ruthenium(II).

ABSTRACT: Reaction of [Ru(Tp)Cl(PPh(3))(2)] (Tp = hydridotrispyrazolyl-borate) with ammonium dithio-benzoate in methanol leads to the formation of the title compound, [Ru(C(9)H(10)BN(6))(C(7)H(5)S(2))(C(18)H(15)P)]. In the crystal structure, the Ru atom is coordinated by three N atoms of the Tp ligand, one P atom of the triphenyl-phosphine ligand and the two S atoms of the dithio-benzoate ligand within a slightly distorted octa-hedron. The Ru-S bonds are slightly different [2.321?(1) and 2.396?(1)?Å] and the average N-Ru-N angle is 86.31°.

SUBMITTER: Lin CH

PROVIDER: S-EPMC2960112 | biostudies-literature | 2008 Nov

REPOSITORIES: biostudies-literature

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(Dithio-benzoato-κS,S')[hydridotris(pyrazol-1-yl-κN)borato](triphenyl-phosphine-κP)ruthenium(II).

Lin Chia-Her CH Liang Yao-Ren YR Tong Hung-Chun HC Lo Yih Hsing YH Kuo Ting Shen TS

Acta crystallographica. Section E, Structure reports online 20081113 Pt 12

Reaction of [Ru(Tp)Cl(PPh(3))(2)] (Tp = hydridotrispyrazolyl-borate) with ammonium dithio-benzoate in methanol leads to the formation of the title compound, [Ru(C(9)H(10)BN(6))(C(7)H(5)S(2))(C(18)H(15)P)]. In the crystal structure, the Ru atom is coordinated by three N atoms of the Tp ligand, one P atom of the triphenyl-phosphine ligand and the two S atoms of the dithio-benzoate ligand within a slightly distorted octa-hedron. The Ru-S bonds are slightly different [2.321 (1) and 2.396 (1) Å] and ...[more]

PMID: 21581150

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