Ontology highlight
ABSTRACT:
SUBMITTER: Hu TC
PROVIDER: S-EPMC3515116 | biostudies-literature | 2012 Nov
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20121013 Pt 11
In the title compound, [Ru(CO)(NH(3))(C(9)H(10)BN(6))(C(18)H(15)P)]Cl·2CH(2)Cl(2), the coordination environment around the Ru(II) atom is distorted octa-hedral. One of the Ru-N(Tp) [Tp = hydridotris(pyrazol-1-yl)borate] bond lengths is slightly longer than the other two as a result of the influence of the trans CO ligand. In the crystal, N-H⋯Cl hydrogen bonds link the complex cations and Cl(-) anions. π-π inter-actions between the pyrazole rings [centroid-centroid distance = 3.764 (3) Å] are als ...[more]