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(Ammine)(carbon-yl)[hydridotris(pyrazol-1-yl-?N(2))borato](triphenyl-phosphine-?P)ruthenium(II) chloride dichloro-methane disolvate.

ABSTRACT: In the title compound, [Ru(CO)(NH(3))(C(9)H(10)BN(6))(C(18)H(15)P)]Cl·2CH(2)Cl(2), the coordination environment around the Ru(II) atom is distorted octa-hedral. One of the Ru-N(Tp) [Tp = hydridotris(pyrazol-1-yl)borate] bond lengths is slightly longer than the other two as a result of the influence of the trans CO ligand. In the crystal, N-H?Cl hydrogen bonds link the complex cations and Cl(-) anions. ?-? inter-actions between the pyrazole rings [centroid-centroid distance = 3.764?(3)?Å] are also present.

SUBMITTER: Hu TC

PROVIDER: S-EPMC3515116 | biostudies-literature | 2012 Nov

REPOSITORIES: biostudies-literature

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(Ammine)(carbon-yl)[hydridotris(pyrazol-1-yl-κN(2))borato](triphenyl-phosphine-κP)ruthenium(II) chloride dichloro-methane disolvate.

Hu Ting-Chuan TC Ye Jun-Xlan JX He Sheng-Ting ST Chiang Guan-Ru GR Lo Yih-Hsing YH

Acta crystallographica. Section E, Structure reports online 20121013 Pt 11

In the title compound, [Ru(CO)(NH(3))(C(9)H(10)BN(6))(C(18)H(15)P)]Cl·2CH(2)Cl(2), the coordination environment around the Ru(II) atom is distorted octa-hedral. One of the Ru-N(Tp) [Tp = hydridotris(pyrazol-1-yl)borate] bond lengths is slightly longer than the other two as a result of the influence of the trans CO ligand. In the crystal, N-H⋯Cl hydrogen bonds link the complex cations and Cl(-) anions. π-π inter-actions between the pyrazole rings [centroid-centroid distance = 3.764 (3) Å] are als ...[more]

PMID: 23284343

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