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1-Diphenyl-phosphino-1'-(diphenyl-phosphinoyl)cobaltocenium hexa-fluorido-phosphate.

ABSTRACT: The title compound, [Co(C(17)H(14)OP)(C(17)H(14)P)]PF(6), was obtained unintentionally as the product of an attempted synthesis of [1,1'-bis-(oxodiphenyl-phospho-ranyl)cobaltocenium] hexa-fluorido-phosphate. The O atom of the oxo group is disordered over two positions with site occupancies of 0.65:0.35. The crystal structure contains weak inter-molecular C-H?F hydrogen bonds, connecting the components of the structure into chains parallel to [010].

SUBMITTER: Wu XH

PROVIDER: S-EPMC2959285 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature

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1-Diphenyl-phosphino-1'-(diphenyl-phosphinoyl)cobaltocenium hexa-fluorido-phosphate.

Wu Xiang-Hua XH Guo Rui R Jin Shan S Yu Guang-Ao GA Liu Sheng-Hua SH

Acta crystallographica. Section E, Structure reports online 20080906 Pt 10

The title compound, [Co(C(17)H(14)OP)(C(17)H(14)P)]PF(6), was obtained unintentionally as the product of an attempted synthesis of [1,1'-bis-(oxodiphenyl-phospho-ranyl)cobaltocenium] hexa-fluorido-phosphate. The O atom of the oxo group is disordered over two positions with site occupancies of 0.65:0.35. The crystal structure contains weak inter-molecular C-H⋯F hydrogen bonds, connecting the components of the structure into chains parallel to [010]. ...[more]

PMID: 21201004

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