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{Bis[2-(diphenyl-phosphino)phen-yl] ether-?P:P'}(dimethyl 2,2'-biphenyl-4,4'-dicarboxyl-ate-?N:N')copper(I) hexa-fluorido-phosphate acetonitrile solvate.

ABSTRACT: In the title compound, [Cu(C(14)H(12)N(2)O(4))(C(36)H(28)OP(2))]PF(6)·CH(3)CN, the Cu(I) ion is coordinated by two N atoms from the dimethyl 2,2'-biphenyl-4,4'-dicarboxyl-ate ligand and two P atoms from the bis-[2-(diphenyl-phosphino)phen-yl] ether ligand in a distorted tetra-hedral environment. In the cation, the short distance of 3.870?(4)?Å between the centroids of the benzene and phenyl rings suggests the existence of intra-molecular ?-? inter-actions.

SUBMITTER: Yu AG

PROVIDER: S-EPMC2977378 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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{Bis[2-(diphenyl-phosphino)phen-yl] ether-κP:P'}(dimethyl 2,2'-biphenyl-4,4'-dicarboxyl-ate-κN:N')copper(I) hexa-fluorido-phosphate acetonitrile solvate.

Yu Ai-Guo AG Zhang Ming M Yang Guang-Di GD Ye Ling L Ma Yu-Guang YG

Acta crystallographica. Section E, Structure reports online 20090704 Pt 8

In the title compound, [Cu(C(14)H(12)N(2)O(4))(C(36)H(28)OP(2))]PF(6)·CH(3)CN, the Cu(I) ion is coordinated by two N atoms from the dimethyl 2,2'-biphenyl-4,4'-dicarboxyl-ate ligand and two P atoms from the bis-[2-(diphenyl-phosphino)phen-yl] ether ligand in a distorted tetra-hedral environment. In the cation, the short distance of 3.870 (4) Å between the centroids of the benzene and phenyl rings suggests the existence of intra-molecular π-π inter-actions. ...[more]

PMID: 21583340

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