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?-3-Thienylmalonato-?O:O-bis-[triphenyl-tin(IV)].

ABSTRACT: The title compound, [Sn(2)(C(6)H(5))(6)(C(7)H(4)O(4)S)], contains two molecules with similar conformations in the asymmetric unit. In each mol-ecule, the Sn atoms adopt a distorted tetra-hedral geometry arising from three C atoms of three phenyl rings and one O atom from the bridging 3-thienylmalonato ligand. The mol-ecules lie about inversion centers with the ligands facing each other, with C?O distances of 3.417?(10) and 3.475?(10)?Å.

SUBMITTER: Yang M

PROVIDER: S-EPMC2959414 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature

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μ-3-Thienylmalonato-κO:O-bis-[triphenyl-tin(IV)].

Yang Minglei M Yin Handong H Wang Daqi D Quan Li L Cui Liansheng L

Acta crystallographica. Section E, Structure reports online 20080924 Pt 10

The title compound, [Sn(2)(C(6)H(5))(6)(C(7)H(4)O(4)S)], contains two molecules with similar conformations in the asymmetric unit. In each mol-ecule, the Sn atoms adopt a distorted tetra-hedral geometry arising from three C atoms of three phenyl rings and one O atom from the bridging 3-thienylmalonato ligand. The mol-ecules lie about inversion centers with the ligands facing each other, with C⋯O distances of 3.417 (10) and 3.475 (10) Å. ...[more]

PMID: 21201052

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