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[1,2-Bis(diphenyl-phosphino)ethane-?P,P'](2-carboxyl-atothio-phenolato-?O,S)nickel(II) methanol solvate.

ABSTRACT: In the title complex, [Ni(C(7)H(4)O(2)S)(C(26)H(24)P(2))]·CH(3)OH, the nickel(II) centre adopts an approximately square-planar geometry, with the Ni atom coordinating to the S and O atoms of the bidentate thio-salicylate ligand and the two P atoms of the chelating Ph(2)PCH(2)CH(2)PPh(2) ligand. There is hydrogen bonding between the methanol solvent mol-ecule and the carbonyl O atom of the thio-salicylate ligand.

SUBMITTER: Miao J

PROVIDER: S-EPMC2968203 | biostudies-literature | 2009 Jan

REPOSITORIES: biostudies-literature

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[1,2-Bis(diphenyl-phosphino)ethane-κP,P'](2-carboxyl-atothio-phenolato-κO,S)nickel(II) methanol solvate.

Miao Jinling J Li Furong F Chen Haiyan H Wang Daqi D Nie Yong Y

Acta crystallographica. Section E, Structure reports online 20090108 Pt 2

In the title complex, [Ni(C(7)H(4)O(2)S)(C(26)H(24)P(2))]·CH(3)OH, the nickel(II) centre adopts an approximately square-planar geometry, with the Ni atom coordinating to the S and O atoms of the bidentate thio-salicylate ligand and the two P atoms of the chelating Ph(2)PCH(2)CH(2)PPh(2) ligand. There is hydrogen bonding between the methanol solvent mol-ecule and the carbonyl O atom of the thio-salicylate ligand. ...[more]

PMID: 21581768

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