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(Benzophenone imine-?N)-chlorido(hydrido-tripyrazolyl-borato)-(triphenyl-phosphine)ruthenium(II) diethyl ether solvate.

ABSTRACT: The reaction of RuCl(Tp)(Ph(3)P)(2), where Tp is [(CH)(3)N(2)](3)BH, with benzophenone imine leads to the formation of the title compound, [Ru(C(9)H(10)BN(6))Cl(C(13)H(11)N)(C(18)H(15)P)]·C(4)H(10)O. The environment about the Ru atom corresponds to a slightly distorted octa-hedron and the bite angle of the Tp ligand produces an average N-Ru-N angle of 86.3?(9)°. The three Ru-N(Tp) bond lengths [2.117?(2), 2.079?(2) and 2.084?(2)?Å] are slightly longer than the average distance (2.038?Å) in other ruthenium-Tp complexes.

SUBMITTER: Tong HC

PROVIDER: S-EPMC2959639 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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(Benzophenone imine-κN)-chlorido(hydrido-tripyrazolyl-borato)-(triphenyl-phosphine)ruthenium(II) diethyl ether solvate.

Tong Hung-Chun HC Hsu Chih-Yung Chen CY Lo Yih-Hsing YH Lin Chia-Her CH Wang Yu Y

Acta crystallographica. Section E, Structure reports online 20081022 Pt 11

The reaction of RuCl(Tp)(Ph(3)P)(2), where Tp is [(CH)(3)N(2)](3)BH, with benzophenone imine leads to the formation of the title compound, [Ru(C(9)H(10)BN(6))Cl(C(13)H(11)N)(C(18)H(15)P)]·C(4)H(10)O. The environment about the Ru atom corresponds to a slightly distorted octa-hedron and the bite angle of the Tp ligand produces an average N-Ru-N angle of 86.3 (9)°. The three Ru-N(Tp) bond lengths [2.117 (2), 2.079 (2) and 2.084 (2) Å] are slightly longer than the average distance (2.038 Å) in other ...[more]

PMID: 21580892

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