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Bis(triphenyl-phosphine-?P)(tropolonato-?O,O')silver(I) dichloro-methane solvate.

ABSTRACT: The title compound, [Ag(C(7)H(5)O(2))(C(18)H(15)P)(2)]·CH(2)Cl(2), crystallizes with a distorted tetra-hedral geometry about the Ag(I) atom, defined by two O atoms from one tropolonate ligand and two P atoms from two triphenyl-phosphine ligands. It is an example of a new type of tropolone derivative that has not been characterized via solid-state methods.

SUBMITTER: Steyl G

PROVIDER: S-EPMC2968127 | biostudies-literature | 2009 Jan

REPOSITORIES: biostudies-literature

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Bis(triphenyl-phosphine-κP)(tropolonato-κO,O')silver(I) dichloro-methane solvate.

Steyl Gideon G Hill Tania N TN

Acta crystallographica. Section E, Structure reports online 20090128 Pt 2

The title compound, [Ag(C(7)H(5)O(2))(C(18)H(15)P)(2)]·CH(2)Cl(2), crystallizes with a distorted tetra-hedral geometry about the Ag(I) atom, defined by two O atoms from one tropolonate ligand and two P atoms from two triphenyl-phosphine ligands. It is an example of a new type of tropolone derivative that has not been characterized via solid-state methods. ...[more]

PMID: 21581823

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