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Tetra-kis[3-(2-pyridylamino)pyridine-?N]nickel(II) diperchlorate ethanol disolvate.

ABSTRACT: In the title compound, [Ni(C(10)H(9)N(3))(4)](ClO(4))(2)·2C(2)H(5)OH, the metal centre exhibits a four-coordinated environment with four pyridine N atoms of the four different dipyridylamine ligands. A twofold rotation axis passes through the Ni atom. N-H?O and N-H?N hydrogen bonds are present in the crystal structure.

SUBMITTER: Wang ZM 

PROVIDER: S-EPMC2961010 | biostudies-literature | 2008 Mar

REPOSITORIES: biostudies-literature

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Tetra-kis[3-(2-pyridylamino)pyridine-κN]nickel(II) diperchlorate ethanol disolvate.

Wang Zhi-Min ZM  

Acta crystallographica. Section E, Structure reports online 20080314 Pt 4

In the title compound, [Ni(C(10)H(9)N(3))(4)](ClO(4))(2)·2C(2)H(5)OH, the metal centre exhibits a four-coordinated environment with four pyridine N atoms of the four different dipyridylamine ligands. A twofold rotation axis passes through the Ni atom. N-H⋯O and N-H⋯N hydrogen bonds are present in the crystal structure. ...[more]

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