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Bromido-1?Br-tricarbonyl-2?C-(2?-cyclo-penta-dien-yl)molybdenum(I)tungsten(I)(W-Mo).

ABSTRACT: The title compound, [WMoBr(C(5)H(5))(CO)(3)], is built up from a pseudo-square-pyramidal piano-stool coordination around the Mo atom, the important geometry being Mo-W = 2.6872?(7)?Å, W-Br = 2.5591?(9)?Å and Mo-W-Br = 158.35?(3)°.

SUBMITTER: Onani MO

PROVIDER: S-EPMC2961464 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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Bromido-1κBr-tricarbonyl-2κC-(2η-cyclo-penta-dien-yl)molybdenum(I)tungsten(I)(W-Mo).

Onani Martin O MO Gertenbach Jan-André JA Bala Muhammad D MD

Acta crystallographica. Section E, Structure reports online 20080507 Pt 6

The title compound, [WMoBr(C(5)H(5))(CO)(3)], is built up from a pseudo-square-pyramidal piano-stool coordination around the Mo atom, the important geometry being Mo-W = 2.6872 (7) Å, W-Br = 2.5591 (9) Å and Mo-W-Br = 158.35 (3)°. ...[more]

PMID: 21202470

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