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(Amino-acetato-?O,N)bis-(quinolin-8-olato-?O,N)cobalt(III) methanol solvate.

ABSTRACT: In the crystal structure of the title compound, [Co(C(2)H(4)NO(2))(C(9)H(6)NO)(2)]·CH(3)OH, the Co(III) atom is chelated by two quinolin-8-olate and one glycinate anions in a distorted octa-hedral coordination geometry. The five-membered chelating glycinate ring assumes an envelope conformation. The complex mol-ecules are assembled by inter-molecular N-H?O hydrogen bonding.

SUBMITTER: Jing BQ

PROVIDER: S-EPMC2961573 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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(Amino-acetato-κO,N)bis-(quinolin-8-olato-κO,N)cobalt(III) methanol solvate.

Jing Bu-Qin BQ Meng Shuang-Ming SM Han Jing J Wang Bin B Li Xue-Mei XM

Acta crystallographica. Section E, Structure reports online 20080510 Pt 6

In the crystal structure of the title compound, [Co(C(2)H(4)NO(2))(C(9)H(6)NO)(2)]·CH(3)OH, the Co(III) atom is chelated by two quinolin-8-olate and one glycinate anions in a distorted octa-hedral coordination geometry. The five-membered chelating glycinate ring assumes an envelope conformation. The complex mol-ecules are assembled by inter-molecular N-H⋯O hydrogen bonding. ...[more]

PMID: 21202483

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