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Tetra-chlorido(1,10-phenanthroline-?N,N')platinum(IV) acetonitrile hemisolvate.

ABSTRACT: The asymmetric unit of the title compound, [PtCl(4)(C(12)H(8)N(2))]·0.5CH(3)CN, contains two crystallographically independent Pt(IV) complexes with very similar geometry and one solvent mol-ecule. In the complexes, each Pt(IV) ion is six-coordinated in a distorted octa-hedral environment by two N atoms of the 1,10-phenanthroline ligand and four Cl atoms. Because of the different trans effects of the N and Cl atoms, the Pt-Cl bonds trans to the N atom are slightly shorter than those trans to the Cl atom. The compound displays numerous inter-molecular ?-? inter-actions between six-membered rings, with a shortest centroid-to-centroid distance of 3.654?Å. There are also weak intra- and inter-molecular C-H?Cl hydrogen bonds.

SUBMITTER: Kim NH

PROVIDER: S-EPMC2968349 | biostudies-literature | 2009 Jan

REPOSITORIES: biostudies-literature

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Tetra-chlorido(1,10-phenanthroline-κN,N')platinum(IV) acetonitrile hemisolvate.

Kim Nam-Ho NH Hwang In-Chul IC Ha Kwang K

Acta crystallographica. Section E, Structure reports online 20090123 Pt 2

The asymmetric unit of the title compound, [PtCl(4)(C(12)H(8)N(2))]·0.5CH(3)CN, contains two crystallographically independent Pt(IV) complexes with very similar geometry and one solvent mol-ecule. In the complexes, each Pt(IV) ion is six-coordinated in a distorted octa-hedral environment by two N atoms of the 1,10-phenanthroline ligand and four Cl atoms. Because of the different trans effects of the N and Cl atoms, the Pt-Cl bonds trans to the N atom are slightly shorter than those trans to the ...[more]

PMID: 21581815

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Tetra-chlorido(1,10-phenanthroline-?N,N')platinum(IV) monohydrate.

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