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[N,N-Bis(diphenyl-phosphino)isopropyl-amine]dibromidonickel(II).

ABSTRACT: The title compound, [NiBr(2)(C(27)H(27)NP(2))], was synthesized by the reaction of NiBr(2)(dme) (dme is 1,2-dimethoxy-ethane) with N,N-bis-(diphenyl-phosphino)isopropyl-amine in methanol/tetra-hydro-furan. The nickel(II) center is coordinated by two P atoms of the chelating PNP ligand, Ph(2)PN(iPr)PPh(2), and two bromide ions in a distorted square-planar geometry.

SUBMITTER: Hapke M

PROVIDER: S-EPMC2968448 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature

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[N,N-Bis(diphenyl-phosphino)isopropyl-amine]dibromidonickel(II).

Hapke Marko M Wöhl Anina A Peitz Stephan S Müller Bernd H BH Spannenberg Anke A Rosenthal Uwe U

Acta crystallographica. Section E, Structure reports online 20090206 Pt 3

The title compound, [NiBr(2)(C(27)H(27)NP(2))], was synthesized by the reaction of NiBr(2)(dme) (dme is 1,2-dimethoxy-ethane) with N,N-bis-(diphenyl-phosphino)isopropyl-amine in methanol/tetra-hydro-furan. The nickel(II) center is coordinated by two P atoms of the chelating PNP ligand, Ph(2)PN(iPr)PPh(2), and two bromide ions in a distorted square-planar geometry. ...[more]

PMID: 21582045

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