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The ansa-bridged cyclo-penta-dienyl titanium complex [{?-C(5)Me(4)CH(2)-C(NMe(2))=N}TiCl(2)].

ABSTRACT: The title complex, dichlorido[N,N-di-methyl-2-(?(5)-tetra-methyl-cyclo-penta-dien-yl)acetamidinido-?N']titanium(IV), [Ti(C(13)H(20)N(2))Cl(2)], exhibits an unusual ansa-bridged conformation. The cyclo-penta-dienyl ring and the mean plane of the Ti-N=C-C-C fragment form a dihedral angle of 88.08?(11)°.

SUBMITTER: Guo D

PROVIDER: S-EPMC2969701 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

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The ansa-bridged cyclo-penta-dienyl titanium complex [{η-C(5)Me(4)CH(2)-C(NMe(2))=N}TiCl(2)].

Guo Donglong D Tong Hong-Bo HB Zhou Meisu M

Acta crystallographica. Section E, Structure reports online 20090507 Pt 6

The title complex, dichlorido[N,N-di-methyl-2-(η(5)-tetra-methyl-cyclo-penta-dien-yl)acetamidinido-κN']titanium(IV), [Ti(C(13)H(20)N(2))Cl(2)], exhibits an unusual ansa-bridged conformation. The cyclo-penta-dienyl ring and the mean plane of the Ti-N=C-C-C fragment form a dihedral angle of 88.08 (11)°. ...[more]

PMID: 21582982

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