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Catena-Poly[[[aqua-(2,2'-bipyridine)manganese(II)]-?-5-methoxy-iso-phthalato-?O,O':O''] monohydrate].

ABSTRACT: In the title compound, {[Mn(C(8)H(4)O(4))(C(10)H(8)N(2))(H(2)O)]·H(2)O}(n), the Mn(II) centre is octa-hedrally coordinated by three O atoms from two 5-methoxy-isophthalate (CH(3)O-ip) ligands, a fourth from a coordinated water mol-ecule and two N atoms from one chelating 2,2'-bipyridine (2,2-bipy) ligand. Each pair of adjacent Mn(II) atoms is bridged by a CH(3)O-ip ligand, forming a helical chain running along a crystallographic 2(1) axis in the c-axis direction. These chains are decorated with 2,2'-bipy ligands on alternating sides. O-H?O hydrogen bonding involving the water molecules stabilizes the crystal structure.

SUBMITTER: Shen SM

PROVIDER: S-EPMC2970467 | biostudies-literature | 2009 Sep

REPOSITORIES: biostudies-literature

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catena-Poly[[[aqua-(2,2'-bipyridine)manganese(II)]-μ-5-methoxy-iso-phthalato-κO,O':O''] monohydrate].

Shen Su-Mei SM

Acta crystallographica. Section E, Structure reports online 20090905 Pt 10

In the title compound, {[Mn(C(8)H(4)O(4))(C(10)H(8)N(2))(H(2)O)]·H(2)O}(n), the Mn(II) centre is octa-hedrally coordinated by three O atoms from two 5-methoxy-isophthalate (CH(3)O-ip) ligands, a fourth from a coordinated water mol-ecule and two N atoms from one chelating 2,2'-bipyridine (2,2-bipy) ligand. Each pair of adjacent Mn(II) atoms is bridged by a CH(3)O-ip ligand, forming a helical chain running along a crystallographic 2(1) axis in the c-axis direction. These chains are decorated with ...[more]

PMID: 21577709

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