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[(Z)-O-Ethyl-N-(o-tol-yl)thio-carbamato-κS](triphenyl-phosphine-κP)gold(I).

ABSTRACT: The title compound, [Au(C(10)H(12)NOS)(C(18)H(15)P)], features a linear geometry for the Au atom defined by the S and P donor atoms. A small deviation from the ideal geometry is noted and is ascribed to an intra-molecular Au⋯O contact [2.936 (4) Å]. Inversion dimers are formed in the crystal structure mediated by C-H⋯π inter-actions between centrosymmetrically related o-tolyl residues [C⋯Cg = 3.532 (6) Å].

SUBMITTER: Tadbuppa PP

PROVIDER: S-EPMC2971922 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

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[(Z)-O-Ethyl-N-(o-tol-yl)thio-carbamato-κS](triphenyl-phosphine-κP)gold(I).

Tadbuppa Primjira P PP Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20091121 Pt 12

The title compound, [Au(C(10)H(12)NOS)(C(18)H(15)P)], features a linear geometry for the Au atom defined by the S and P donor atoms. A small deviation from the ideal geometry is noted and is ascribed to an intra-molecular Au⋯O contact [2.936 (4) Å]. Inversion dimers are formed in the crystal structure mediated by C-H⋯π inter-actions between centrosymmetrically related o-tolyl residues [C⋯Cg = 3.532 (6) Å]. ...[more]

PMID: 21578636

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