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[(Z)-O-Ethyl-N-(o-tol-yl)thio-carbamato-κS](triphenyl-phosphine-κP)gold(I).

ABSTRACT: The title compound, [Au(C(10)H(12)NOS)(C(18)H(15)P)], features a linear geometry for the Au atom defined by the S and P donor atoms. A small deviation from the ideal geometry is noted and is ascribed to an intra-molecular Au⋯O contact [2.936 (4) Å]. Inversion dimers are formed in the crystal structure mediated by C-H⋯π inter-actions between centrosymmetrically related o-tolyl residues [C⋯Cg = 3.532 (6) Å].

SUBMITTER: Tadbuppa PP

PROVIDER: S-EPMC2971922 | biostudies-literature |

REPOSITORIES: biostudies-literature

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[(Z)-N-(2-Chloro-phen-yl)-O-ethyl-thio-carbamato-κS](triphenyl-phosphine-κP)gold(I).

Project description:The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)], features a linear S,P-donor set with a small deviation from the ideal linear geometry due to the proximity of the meth-oxy O atom to Au [Au⋯O = 2.986 (4) Å].

| S-EPMC2971960 | biostudies-literature

[(Z)-O-Ethyl-N-(p-tol-yl)thio-carbamato-?S](triphenyl-phosphine)-?P]gold(I).

Project description:The title compound, [Au(C(10)H(12)NOS)(C(18)H(15)P)], features a linear S,P-donor set about the central Au atom. The thio-carbamate ligand is orientated to place the aryl ring in close proximity to Au [the closest Au?C distance is 3.238?(4)?Å], which results in a small deviation from the ideal linear P-Au-S geometry.

| S-EPMC2972054 | biostudies-literature

[(Z)-N,O-Disopropyl-thio-carbamato-κS](tricyclo-hexyl-phosphine-κP)gold(I).

Project description:In the title compound, [Au(C(7)H(14)NOS)(C(18)H(33)P)], the Au(I) atom is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.94 (2)°], with the distortion due to a short intra-molecular Au⋯O contact [2.908 (2) Å].

| S-EPMC2971935 | biostudies-literature

[(Z)-O-Ethyl-N-propyl-thio-carbamato-?S](triphenyl-phosphine-?P)gold(I).

Project description:The title compound, [Au(C(6)H(12)NOS)(C(18)H(15)P)], features a linear S,P-donor set about the central Au atom with a deviation from linearity [S-Au-P = 176.66?(5)°] due to an intra-molecular Au?O contact [2.991?(5)?Å]. Supra-molecular dimers are formed in the crystal structure mediated by C-H?N inter-actions.

| S-EPMC2971786 | biostudies-literature

[O-Ethyl N-(4-nitro-phen-yl)thio-carbam-ato-κS](tri-p-tolyl-phosphine-κP)gold(I).

Project description:A nearly linear coordination geometry for Au is found in the title compound, [Au(C(9)H(9)N(2)O(3)S)(C(21)H(21)P)]. The thio-carbamate ligand is orientated so that the aryl group is in close proximity to the Au atom, consistent with an Au⋯π contact [Au⋯Cg = 3.351 (5) Å; Cg is the centroid of the aromatic ring].

| S-EPMC2959883 | biostudies-literature

[(Z)-O-Ethyl N-(4-chloro-phen-yl)thio-carbamato-?S](triphenyl-phosphine-?P)gold(I) dichloro-methane hemisolvate.

Project description:The Au(I) atom in the title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)]·0.5CH(2)Cl(2), exists within a slightly distorted linear geometry defined by an S,P donor set [S-Au-P angle = 178.01?(4)°]; a close intra-molecular Au?O contact [2.964?(4)?Å] also occurs. In the crystal structure, mol-ecules are linked into supra-molecular chains propagating along [010] by C-H?N, C-H?S and C-H?? inter-actions. The solvent mol-ecule is disordered about a twofold rotation axis.

| S-EPMC2979641 | biostudies-literature

[(Z)-O-Isopropyl N-(m-tol-yl)thio-carbamato-?S](tricyclo-hexyl-phosphine-?P)gold(I).

Project description:The Au atom in the title compound, [Au(C(11)H(14)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.73?(3)°], with the distortion due in part to a close intra-molecular Au?O contact [3.060?(3)?Å]. In the crystal structure, mol-ecules are arranged in layers in the bc plane with the primary connections between the arrays being of the type C-H??.

| S-EPMC2983763 | biostudies-literature

[(Z)-N-(3-Chloro-phen-yl)-O-ethyl-thio-carbamato-?S](triphenyl-phosphine-?P)gold(I).

Project description:The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)], reveals a near linear geometry for the Au atom defined by a S,P-donor set [S-Au-P = 175.86?(3)°]. The deviation from linearity is ascribed to the proximate O atom derived from the thio-carbamato anion [Au?O = 2.967?(3)?Å].

| S-EPMC2971815 | biostudies-other

[(Z)-N-(4-Chloro-phen-yl)-O-methyl-thio-carbamato-?S](triphenyl-phosphine-?P)gold(I).

Project description:The title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], is characterized by a linear S,P-donor set with a small deviation from the ideal linearity [S-Au-P = 175.14?(5)°] due to the close approach of the O atom to the Au atom [Au?O = 2.882?(3)?Å]. Loosely associated dimers are formed in the crystal structure through C-H?O inter-actions.

| S-EPMC2972176 | biostudies-literature

(Ferrocenyl-thio-phospho-nato-κS)(triphenyl-phosphane-κP)gold(I) dichloro-methane monosolvate.

Project description:In the title compound, [AuFe(C(5)H(5))(C(5)H(5)O(2)PS)(C(18)H(15)P)]·CH(2)Cl(2), the two-coordinate gold(I) atom shows a slightly distorted linear arrangement, with a P-Au-S bond angle of 176.81 (6)°. The difference in P=O and P-O(H) bond lengths, which are 1.503 (6) and 1.541 (5) Å, respectively, implies there is apparently no delocalization between the P-O bonds, and the proton appears to be localized on one O atom only. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds link dinuclear mol-ecules into chains propagated in the [010] direction. The dichloro-methane solvent mol-ecule was disordered between two positions in a 0.63 (3):0.37 (3) ratio.

| S-EPMC3008988 | biostudies-literature

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