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[(Z)-O-Ethyl-N-(p-tol-yl)thio-carbamato-?S](triphenyl-phosphine)-?P]gold(I).

ABSTRACT: The title compound, [Au(C(10)H(12)NOS)(C(18)H(15)P)], features a linear S,P-donor set about the central Au atom. The thio-carbamate ligand is orientated to place the aryl ring in close proximity to Au [the closest Au?C distance is 3.238?(4)?Å], which results in a small deviation from the ideal linear P-Au-S geometry.

SUBMITTER: Tadbuppa PP

PROVIDER: S-EPMC2972054 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

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[(Z)-O-Ethyl-N-(p-tol-yl)thio-carbamato-κS](triphenyl-phosphine)-κP]gold(I).

Tadbuppa Primjira P PP Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20091114 Pt 12

The title compound, [Au(C(10)H(12)NOS)(C(18)H(15)P)], features a linear S,P-donor set about the central Au atom. The thio-carbamate ligand is orientated to place the aryl ring in close proximity to Au [the closest Au⋯C distance is 3.238 (4) Å], which results in a small deviation from the ideal linear P-Au-S geometry. ...[more]

PMID: 21578617

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[(Z)-O-Ethyl-N-(o-tol-yl)thio-carbamato-κS](triphenyl-phosphine-κP)gold(I).

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