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[(Z)-O-Methyl-N-propyl-thio-carbamato-?S](triphenyl-phosphine-?P)gold(I).

ABSTRACT: In the title compound, [Au(C(5)H(10)NOS)(C(18)H(15)P)], the Au(I) atom is linearly coordinated within an S,P-donor set with distortion from an ideal linear geometry [S-Au-P = 176.71?(6)°] due to an intra-molecular Au?O contact [2.943?(4)?Å]. In the crystal structure, centrosymmetrically related mol-ecules associate via C-H?O inter-actions.

SUBMITTER: Tadbuppa PP

PROVIDER: S-EPMC2972153 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

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[(Z)-O-Methyl-N-propyl-thio-carbamato-κS](triphenyl-phosphine-κP)gold(I).

Tadbuppa Primjira P PP Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20091111 Pt 12

In the title compound, [Au(C(5)H(10)NOS)(C(18)H(15)P)], the Au(I) atom is linearly coordinated within an S,P-donor set with distortion from an ideal linear geometry [S-Au-P = 176.71 (6)°] due to an intra-molecular Au⋯O contact [2.943 (4) Å]. In the crystal structure, centrosymmetrically related mol-ecules associate via C-H⋯O inter-actions. ...[more]

PMID: 21578595

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