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Tris(ethyl-enediamine-?(2)N,N')nickel(II) bis-(dimethyl phosphate).

ABSTRACT: In the title compound, [Ni(C(2)H(8)N(2))(3)][O(2)P(OCH(3))(2)](2), the Ni(II) atom is six-coordinated in a distorted octa-hedral geometry by six N atoms from three ethyl-enediamine ligands. The P atoms of the anions adopt a distorted tetra-hedral geometry. In the crystal, inter-molecular N-H?O and C-H?O hydrogen bonds link the cations and anions into a three-dimensional network.

SUBMITTER: Rafizadeh M

PROVIDER: S-EPMC3414105 | biostudies-literature | 2012 Aug

REPOSITORIES: biostudies-literature

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Tris(ethyl-enediamine-κ(2)N,N')nickel(II) bis-(dimethyl phosphate).

Rafizadeh Masoud M Saadati Moshtaghin Hamid Reza HR Amani Vahid V

Acta crystallographica. Section E, Structure reports online 20120707 Pt 8

In the title compound, [Ni(C(2)H(8)N(2))(3)][O(2)P(OCH(3))(2)](2), the Ni(II) atom is six-coordinated in a distorted octa-hedral geometry by six N atoms from three ethyl-enediamine ligands. The P atoms of the anions adopt a distorted tetra-hedral geometry. In the crystal, inter-molecular N-H⋯O and C-H⋯O hydrogen bonds link the cations and anions into a three-dimensional network. ...[more]

PMID: 22904712

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