Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

[2-(Tetra-zol-1-yl)acetato-?O]tris-(tri-phenyl-phosphine-?P)silver(I) mono-hydrate.

ABSTRACT: The Ag(I) atom in the title compound, [Ag(C(3)H(3)N(4)O(2))(C(18)H(15)P)(3)]·H(2)O, exists in a distorted tetra-hedral environment. The uncoordinated water mol-ecule forms only one hydrogen bond to the uncoordinated carbonyl O atom.

SUBMITTER: Zhao J

PROVIDER: S-EPMC2972064 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

[2-(Tetra-zol-1-yl)acetato-κO]tris-(tri-phenyl-phosphine-κP)silver(I) mono-hydrate.

Zhao Jun J Hu Zong-Zhi ZZ Zheng Xue-Gang XG Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20091118 Pt 12

The Ag(I) atom in the title compound, [Ag(C(3)H(3)N(4)O(2))(C(18)H(15)P)(3)]·H(2)O, exists in a distorted tetra-hedral environment. The uncoordinated water mol-ecule forms only one hydrogen bond to the uncoordinated carbonyl O atom. ...[more]

PMID: 21578629

Similar Datasets

Crystal structure of di-aqua-(μ2-tri-ethyl-ene-tetra-minehexa-acetato)-dizinc tetra-hydrate.

Project description:The reaction of ZnO and tri-ethyl-ene-tetra-minehexaacetic acid (H6TTHA) in aqueous solution after refluxing yields the binuclear title compound, [Zn2(C18H26N4O12)(H2O)2]·4H2O. There is a centre of symmetry in the [Zn2(H2TTHA)(H2O)2] mol-ecule in the crystalline state. Both Zn(II) ions are octahedrally surrounded and bound by an N2O3 donor set from the H2TTHA(4-) anion and a water mol-ecule; the N atoms are cis and the water mol-ecule is trans to an N atom. The Zn⋯Zn separation is 7.562 (1) Å. An intra-molecular C-H⋯O inter-action is observed and both carboxyl-ate H atoms are disordered over two adjacent sites. In the crystal, the components are linked by O-H⋯O and C-H⋯O hydrogen bonds generating a three-dimensonal network.

| S-EPMC4350722 | biostudies-literature

Di-?-thio-cyanato-bis-[bis-(tri-p-tolyl-phosphine)silver(I)] 0.35-hydrate.

Project description:In the binuclear centrosymmetric title compound, [Ag(2)(NCS)(2)(C(21)H(21)P)(4)]·0.35H(2)O, a pseudo-polymorph of [Ag(2)(NCS)(2)(C(21)H(21)P)(4)]·2CH(3)CN, the Ag atom is coordinated by two phosphine ligands and two bridging thio-cyanate ligands in a distorted tetra-hedral configuration. The crystal structure exhibits inter-molecular C-H?? inter-actions.

| S-EPMC2984055 | biostudies-literature

Tris{4-[(2H-tetra-zol-5-yl)meth-yl]morpholinium} dodeca-tungstophosphate hexa-hydrate.

Project description:The title heteropolyoxidotungstate-based inorganic-organic hybrid material, (C(6)H(12)N(5)O)(3)[W(12)(PO(4))O(36)]·6H(2)O, consists of one α-Keggin-type [W(12)(PO(4))O(36)](3-) polyoxidometalate anion (POM), three crystallographically independent 4-[(2H-tetra-zol-5-yl)meth-yl]morpholinium cations and six water mol-ecules of crystallization. The morpholine ring of the cation adopts a chair conformation. The anion shows characteristic features with respect to bond lengths and angles. An extensive network of N-H⋯O, N-H⋯N, O-H⋯O and O-H⋯N hydrogen-bonding inter-actions between the organic cations, inorganic anion and the crystal water mol-ecules lead to a three-dimensional structure. Moreover, six uncoordinated water mol-ecules increase the number of hydrogen bonds in the network and lead to the formation of (H(2)O)(∞) clusters.

| S-EPMC3052096 | biostudies-literature

Crystal structure of bis-[(acetato-?O)(imidazolidine-2-thione-?S)bis-(tri-phenyl-phosphane-?P)silver(I)] di-?-imidazol-idine-2-thione-?(4) S:S-bis-[(imidazol-id-ine-2-thione-?S)bis-(tri-phenyl-phosphane-?P)silver(I)] di-acetate aceto-nitrile disolvate tetra-hydrate.

Project description:In the title compound, [Ag2(C3H6N2S)4(C18H15P)2](C2H3O2)2·[Ag(C2H3O2)(C3H6N2S)(C18H15P)2]2·2C2H3N·4H2O, the Ag(I) ion in the mononuclear neutral complex exhibits a distorted tetra-hedral environment with coordination by two P atoms from tri-phenyl-phosphane (PPh3) ligands, one S atom of an imidazolidine-2-thione (etu) ligand and one O atom of an acetate anion. The binuclear cationic complex comprises two inversion-related [Ag(C3H6N2S)2(C18H15P)] units with Ag(I) ions bridged by two S atoms from etu ligands forming a four-membered Ag-S-Ag-S ring. Each Ag(I) ion is coordinated by a P atom of a PPh3 ligand, two S atoms of bridging etu ligands and the terminal S atom of an etu ligand in a distorted tetra-hedral environment. In the crystal, the mononuclear complex is linked to lattice water mol-ecules through O-H?O and N-H?O hydrogen bonds, forming a chain along [100]. In addition, the binuclear complex mol-ecules are connected to acetate anions and lattice water mol-ecules via O-H?O, N-H?O and O-H?S hydrogen bonds, also along [100].

| S-EPMC4910330 | biostudies-literature

Crystal structure of bis-[tetra-kis-(tri-phenyl-phosphane-κP)silver(I)] (nitrilo-tri-acetato-κ(4) N,O,O',O'')(tri-phenyl-phosphane-κP)argentate(I) with an unknown amount of methanol as solvate.

Project description:The structure of the title compound, [Ag(C18H15P)4]2[Ag(C6H6NO6)(C18H15P)], exhibits trigonal (P-3) symmetry, with a C 3 axis through all three complex ions, resulting in an asymmetric unit that contains one third of the atoms present in the formula unit. The formula unit thus contains two of the cations, one anion and disordered mol-ecules of methanol as the packing solvent. Attempts to refine the solvent model were unsuccessful, indicating uninter-pretable disorder. Thus, the SQUEEZE procedure in PLATON [Spek (2015 ▸). Acta Cryst. C71, 9-18] was applied, accounting for 670 electrons per unit cell, representing approximately 18 mol-ecules of methanol in the formula unit. The stated crystal data for M r, μ etc do not take these into account.

| S-EPMC4778820 | biostudies-literature

Dichlorido[2,3,5,6-tetra-fluoro-4-(tri-fluoro-meth-yl)phenyl-?C]bis-(tri-methyl-phosphine-?P)cobalt(III).

Project description:In the title compound, [Co(C(7)F(7))Cl(2)(C(3)H(9)P)(2)], the Co(III) atom displays a trigonal-bipyramidal coordination geometry, with the two Cl ligands and the C atom of the perfluoro-tolyl ligand in the equatorial plane and the two phosphine ligands occupying axial positions. The mol-ecule has an approximate C(2v) symmetry. The trifluoro-methyl group is disordered over two positions, with nearly equal occupancies.

| S-EPMC2979265 | biostudies-literature

(Perchlorato-?O)tris-(triphenyl-phosphine-?P)silver(I).

Project description:In the title complex, [Ag(C(18)H(15)P)(3)(ClO(4))], the silver coord-ination environment is dominated by the distorted P(3)AgO tetra-hedron in which Ag-O = 2.608?(12)?Å and the Ag-P bond lengths are 2.5663?(17), 2.5076(16) and 2.5450?(17)?Å. The perchlorate O-atoms are disordered over two positions in a 0.584?(14):0.416?(14) ratio.

| S-EPMC3007391 | biostudies-literature

Crystal structure of bis-(μ2-meth-anolato-κO:κO)hexa-methyl-bis-(μ2-tri-phenyl-acetato-κO:κO')bis-(μ2-tri-phenyl-acetato-κ2 O,O':κO)dialuminiumdi-lanthanum toluene tetra-solvate.

Project description:The title compound, [Al2La2(C20H15O2)4(CH3)6(CH3O)2]·4CH3C6H5 or [{La(Ph3CCOO)2(Me3AlOMe)}2]·4CH3C6H5, was formed in a reaction between lanthanum tris-(tetra-methyl-aluminate) and tri-phenyl-acetic acid (1:1) with unintended partial oxidation. The tri-phenyl-acetate ligand exhibits μ2-κ1 O:κ1 O' bridging and μ2-κ2 O,O':κ1 O semi-bridging coordination modes, forming a dimeric La2(μ-OCO)4 core. The semi-bridging tri-phenyl-acetate group provides additional bonding with an La3+ cation via the π-system of one of its phenyl rings. The tri-methyl-meth-oxy-aluminate anion, which is coordinated to the La3+ cation by its O atom, displays a rather long La-CMe bond. Two toluene mol-ecules are each disordered over two orientations about centres of symmetry with site occupancy factors of 0.5. The title compound represents the first example of an LnIII complex containing both alkyl alkoxide aluminate and π-bounded arene fragments.

| S-EPMC6281095 | biostudies-literature

Di-?-acetato-?O:O-bis-{(acetato-?O,O')bis-[3-(1H-imidazol-1-yl-?N)-1-phenyl-propan-1-one]cadmium} tetra-hydrate.

Project description:In the mol-ecular structure of the title neutral binuclear complex, [Cd(2)(C(2)H(3)O(2))(4)(C(12)H(12)N(2)O)(4)]·4H(2)O, each Cd(II) atom is six-coordinated and exhibits a distorted octa-hedral geometry. Three O atoms from two acetate ions and one monodentate 3-(1H-imidazol-1-yl-?N(3))-1-phenyl-propan-1-one (L) ligand form the equatorial plane, while the bridging-O atom forming the longer Cd-O distance,and the N atom of the second L ligand, forming the longer Cd-N distance, occupy axial positions with an N-Cd-O angle of 170.77?(7)°. Inter-molecular O-H?O hydrogen bonds exist between the lattice water mol-ecules and the acetate ions of adjacent mol-ecules, resulting in a two-dimensional supra-molecular structure.

| S-EPMC3238768 | biostudies-literature

Tris(1,10-phenanthroline)nickel(II) dichromate tetra-hydrate.

Project description:The asymmetric unit of the title compound, [Ni(C(12)H(8)N(2))(3)][Cr(2)O(7)]·4H(2)O, contains one cation, one anion and four water mol-ecules, three of which are disordered over two sites with equal occupancies. In the cation, the metal centre is coordinated by six N atoms from three 1,10-phenanthroline ligands in a distorted octa-hedral geometry. The [Cr(2)O(7)](2-) anion exhibits a staggered conformation. The crystal packing is stabilized by inter-molecular O-H?O hydrogen bonds and ?-? inter-actions, evidenced by short distances of 3.531?(5)?Å between the centroids of aromatic rings.

| S-EPMC2979795 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data