Browse
Submit Data
Databases
API
Help

Dataset Information

19 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Catena-Poly[copper(II)-bis(μ-2,4-dichloro-6-formyl-phenolato)-κO,O':Cl;κCl:O,O'].

ABSTRACT: In the title compound, [Cu(C(7)H(3)Cl(2)O(2))(2)](n), the Cu(II) atom lies on a centre of inversion and adopts a [4+2] coordination mode, with two long axial Cu-Cl coordinative bonds complementing four Cu-O bonds from two 2,4-dichloro-6-formyl-phenolate ligands in a distorted square plane. π-π stacking inter-actions are also formed between neighbouring aromatic rings, with a centroid-centroid separation of 3.624 (2) Å.

SUBMITTER: Fan Y

PROVIDER: S-EPMC2961934 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

catena-Poly[[bis-(μ-2-formyl-6-meth-oxy-phenolato)copper(II)sodium]-μ-nitrato].

Project description:In the title heterodinuclear complex, [CuNa(C(8)H(7)O(3))(2)(NO(3))](n), the Cu(II) ion is five-coordinated in a square-pyramidal arrangement by four atoms of two different ligand molecules in equatorial positions and one remote nitrate O atom in the apical position. The Na(+) ion is eight-coordinated by four ligand O atoms and four nitrate O atoms. The ligand links the Cu(II) and Na ions, forming a layered arrangement extending parallel to (001).

| S-EPMC3246950 | biostudies-literature

Bis(2,4-dibromo-6-formyl-phenolato-κO,O')copper(II).

Project description:In the title compound, [Cu(C(7)H(3)Br(2)O(2))(2)], the Cu(II) atom, which lies on an inversion centre, is coordinated by four O atoms from two chelating bidentate 2,4-dibromo-6-formyl-phenolate ligands in a slightly distorted square-planar coordination geometry. In the crystal structure, short inter-molecular Br⋯Br [3.516 (4) and 3.653 (4) Å] and Cu⋯Br [3.255 (1) Å] contacts together with C-H⋯O hydrogen bonds generate a three-dimensional network.

| S-EPMC2914936 | biostudies-literature

Diaqua-bis(2,4-dichloro-6-formyl-phenolato)zinc(II)-bis-(?-2,4-dichloro-6-formyl-phenolato)bis-[aqua-(2,4-dichloro-6-formyl-phenolato)zinc(II)] (2/1).

Project description:The crystal of the title compound, [Zn(C(7)H(3)Cl(2)O(2))(2)(H(2)O)(2)](2)·[Zn(2)(C(7)H(3)Cl(2)O(2))(4)(H(2)O)(2)], consists of monomeric and dimeric Zn(II) complexes. Both complexes afford a six-coordinated coordination environment about the Zn atoms with cis-configuration ligands. The deprotonated hydr-oxy groups of the 3,5-dichloro-salicylaldehyde ligands bridge two metal cations, forming a centrosymmetric dimeric complex. Inter-molecular O-H?O hydrogen bonding occurs between the coordinated water mol-ecules and deprotonated hydr-oxy groups in the crystal structure.

| S-EPMC2972068 | biostudies-literature

cis-Aqua-bis(2,4-dichloro-6-formyl-phenolato-κO,O')(N,N-dimethyl-formamide-κO)nickel(II).

Project description:In the title compound, [Ni(C(7)H(3)Cl(2)O(2))(2)(C(3)H(7)NO)(H(2)O)], the Ni(II) ion is coordinated by four O atoms from two bidentate 2,4-dichloro-6-formyl-phenolate ligands, one O atom from a water ligand and one O atom from a dimethyl-formamide ligand in a slightly distorted octa-hedral environment. In the crystal structure, centrosymmetric dimers are formed though O-H⋯O and O-H⋯Cl hydrogen bonds; π-π stacking inter-actions, with a centroid-centroid distance of 3.796 (2) Å, are also found.

| S-EPMC2961979 | biostudies-literature

catena-Poly[[aqua-copper(II)]-μ(2)-imino-diacetato-κO,N,O':O'].

Project description:In the title compound, [Cu(C(4)H(5)O(4))(H(2)O)](n), the imino-diacetate (ida) ligands link the Cu(II) atoms into polymeric zigzag chains running along [010]. Each Cu(II) ion is five-coordinated in a distorted square-pyramidal geometry by one N and two O atoms from an ida ligand, one O atom from the neighbouring ida ligand and one water O atom. In the crystal, the polymeric chains are held together via inter-molecular O-H⋯O and N-H⋯O hydrogen bonds.

| S-EPMC3246954 | biostudies-literature

catena-Poly[[tris-(pyridine-κN)copper(II)]-μ-tetra-fluoro-terephthalato-κO:O].

Project description:In the title compound, [Cu(C(8)F(4)O(4))(C(5)H(5)N)(3)](n), the Cu(II) atom, lying on a twofold rotation axis, is five-coordinated by two O atoms from two tetra-fluoro-terephthalate ligands and three N atoms from three pyridine ligands in a distorted trigonal-bipyramidal geometry. Adjacent Cu(II) atoms are connected via the bridging tetra-fluoro-terephthalate ligands into a one-dimensional chain running along the [101] direction.

| S-EPMC2961727 | biostudies-literature

catena-Poly[[diaqua-cadmium(II)]-μ-(methyl morpholino dichloro-methylene-diphospho-nato)-κO,O':O''-[tetra-aqua-cadmium(II)]-μ-(methyl morpholino dichloro-methyl-enediphospho-nato)-κO:O',O''].

Project description:The asymmetric unit of the title compound, [Cd(C(6)H(11)Cl(2)NO(6)P(2))(H(2)O)(3)](n), contains two octahedrally coordinated Cd atoms located in special positions, one on a twofold rotation axis and the other on a centre of symmetry. The metal atoms are connected by methyl morpholino dichloro-methyl-enediphospho-nate ligands into chains in the c-axis direction. These chains are further connected by O-H⋯O hydrogen bonds into a layer-like construction along (100).

| S-EPMC2977635 | biostudies-literature

Poly[μ(3)-aqua-μ(2)-2,4-dinitro-phenolato-rubidium(I)].

Project description:The asymmetric unit of the title compound, [Rb(C(6)H(3)N(2)O(5))(H(2)O)](n), comprises a rubidium cation, a 2,4-dinitro-phenoxide anion and a water mol-ecule. The Rb(+) cation is 11-coordinated by O atoms from 2,4-dinitro-phenolate anions and water mol-ecules. The metal centre is firstly coordinated by two μ(3)-H(2)O to form a one-dimensional ladder-shaped unit, [Rb(2)(μ(3)-H(2)O)(2)], which is further linked by 2,4-dinitro-phenolate to give the three-dimensional framework of the title compound. The crystal structure involves O-H⋯O hydrogen bonds.

| S-EPMC2915150 | biostudies-literature

catena-Poly[[(dimethyl-formamide-κO)copper(II)]-bis-(μ-4-nitro-phenyl-cyanamido-κN:N)].

Project description:In the title compound, [Cu(C(7)H(4)N(3)O(2))(2)(C(3)H(7)NO)], the Cu(II) atom is five-coordinated in a distorted square-pyramidal geometry, with the N atoms in equatorial positions and the dimethyl-formamide O atom in an axial position. The dihedral angle between adjacent benzene rings is 70.33 (12)°.

| S-EPMC2969028 | biostudies-literature

catena-Poly[[[aqua-(propane-1,3-diamine-κN,N')copper(II)]-μ-fumarato-κO:O'] monohydrate].

Project description:The asymmetric unit of the title compound, {[Cu(C(4)H(2)O(4))(C(3)H(10)N(2))(H(2)O)]·H(2)O}(n), consists of two Cu(II) atoms, half each of two propane-1,3-diamine ligands and two coordinated water mol-ecules, all lying on crystallographic mirror planes, also one fumarate dianion and one uncoordinated water mol-ecule in a general position. The Cu(C(3)H(10)N(2))(H(2)O) units are linked via fumarate dianions into a zigzag chain running along the a axis. A longer Cu-O distance [2.873 (3) Å] is to a water mol-ecule bridging equivalent Cu(II) atoms in adjacent chains, forming a three-dimensional framework. One of the Cu(II) atoms is in a distorted square-pyramidal environment and the other is in a pseudo-octa-hedral geometry of the [5+1] type. O-H⋯O and N-H⋯O hydrogen bonds are observed in the crystal structure.

| S-EPMC2960309 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data