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Tetra-ethyl-ammonium 12-phenyl-ethynylcarba-closo-dodeca-borate, [Et(4)N][12-PhCC-closo-CB(11)H(11)].

ABSTRACT: The asymmetric unit of the title compound, C(8)H(20)N(+)·C(9)H(16)B(11) (-) or [Et(4)N][12-PhCC-closo-CB(11)H(11)], consists of one cation and one anion. The [12-PhCC-closo-CB(11)H(11)](-) anion is close to possessing a non-crystallographic plane of mirror symmetry with a nearly linear B-C C-C group, with B-C C and C C-C angles of 177.15?(16) and 176.64?(17)°, respectively.

SUBMITTER: Finze M

PROVIDER: S-EPMC2977730 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

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Tetra-ethyl-ammonium 12-phenyl-ethynylcarba-closo-dodeca-borate, [Et(4)N][12-PhCC-closo-CB(11)H(11)].

Finze Maik M Reiss Guido J GJ

Acta crystallographica. Section E, Structure reports online 20090418 Pt 5

The asymmetric unit of the title compound, C(8)H(20)N(+)·C(9)H(16)B(11) (-) or [Et(4)N][12-PhCC-closo-CB(11)H(11)], consists of one cation and one anion. The [12-PhCC-closo-CB(11)H(11)](-) anion is close to possessing a non-crystallographic plane of mirror symmetry with a nearly linear B-C C-C group, with B-C C and C C-C angles of 177.15 (16) and 176.64 (17)°, respectively. ...[more]

PMID: 21583866

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