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Cyclo-hexyldimethyl-ammonium tetra-hydroxy-penta-borate.

ABSTRACT: The title compound, [C(8)H(18)N](+)·[B(5)O(6)(OH)(4)](-), has been synthesized under mild solvothermal conditions in the presence of N,N-dimethyl-cyclo-hexyl-amine acting as a template. The structure consists of penta-borate [B(5)O(6)(OH)(4)](-) anions connected through O-H?O hydrogen bonds into a three-dimensional framework, with large channels along [100], [010] and [001] directions. The [C(8)H(18)N](+) cations reside in the channels, inter-acting with the framework through N-H?O hydrogen bonds.

SUBMITTER: Li H

PROVIDER: S-EPMC2959341 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature

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Cyclo-hexyldimethyl-ammonium tetra-hydroxy-penta-borate.

Li Hui H Wang Guo-Ming GM Xue Shu-Yun SY Liang Qiang Q

Acta crystallographica. Section E, Structure reports online 20080917 Pt 10

The title compound, [C(8)H(18)N](+)·[B(5)O(6)(OH)(4)](-), has been synthesized under mild solvothermal conditions in the presence of N,N-dimethyl-cyclo-hexyl-amine acting as a template. The structure consists of penta-borate [B(5)O(6)(OH)(4)](-) anions connected through O-H⋯O hydrogen bonds into a three-dimensional framework, with large channels along [100], [010] and [001] directions. The [C(8)H(18)N](+) cations reside in the channels, inter-acting with the framework through N-H⋯O hydrogen bond ...[more]

PMID: 21201021

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