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Trans-(2,2'-Bipyrimidine)diiodido(isopropoxido)oxidorhenium(V).


ABSTRACT: In the title compound, [Re(C(3)H(7)O)I(2)O(C(8)H(6)N(4))], the Re(V) atom adopts a distorted octa-hedral ReI(2)O(2)N(2) geometry, with the O atoms in a trans conformation and the I atoms in a cis conformation. Two intra-molecular C-H?I contacts occur. The crystal structure is stabilized by inter-molecular C-H?O, C-H?N and C-H?I hydrogen bonds.

SUBMITTER: Kochel A 

PROVIDER: S-EPMC2980033 | biostudies-literature | 2009

REPOSITORIES: biostudies-literature

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trans-(2,2'-Bipyrimidine)diiodido(isopropoxido)oxidorhenium(V).

Kochel Andrzej A  

Acta crystallographica. Section E, Structure reports online 20091212 Pt 1


In the title compound, [Re(C(3)H(7)O)I(2)O(C(8)H(6)N(4))], the Re(V) atom adopts a distorted octa-hedral ReI(2)O(2)N(2) geometry, with the O atoms in a trans conformation and the I atoms in a cis conformation. Two intra-molecular C-H⋯I contacts occur. The crystal structure is stabilized by inter-molecular C-H⋯O, C-H⋯N and C-H⋯I hydrogen bonds. ...[more]

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