Cis-Aqua-bis-(2,2'-bipyrimidine-?N,N)iodidomanganese(II) iodide monohydrate.

ABSTRACT: The asymmetric unit of the title compound, [MnI(C(8)H(6)N(4))(2)(H(2)O)]I·H(2)O, consists of a cationic Mn(II) complex, an I(-) anion and a solvent water mol-ecule. In the complex, the Mn(II) ion is six-coordinated in a distorted octa-hedral environment defined by four N atoms of the two chelating 2,2'-bipyrimidine (bpym) ligands, one I(-) anion and one O atom of a water ligand. The dihedral angle between the least-squares planes of the two bpym ligands [maximum deviation = 0.092?(7)?Å] is 79.9?(1)°. In the crystal, the complex, anion and solvent water mol-ecule are linked by inter-molecular O-H?O, O-H?I and O-H?N hydrogen bonds.

SUBMITTER: Ha K 

PROVIDER: S-EPMC3201340 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature