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Cis-Bis(2,2'-bipyrimidine-?N,N)di-iodidomanganese(II).

ABSTRACT: The asymmetric unit of the title complex, [MnI(2)(C(8)H(6)N(4))(2)], contains one half of a neutral Mn(II) complex, with the entire molecule completed by the application of twofold symmetry. The Mn(II) ion is six-coordinated in a distorted octa-hedral environment defined by four N atoms of the two chelating 2,2'-bipyrimidine (bpym) ligands and two I(-) anions in a cis-N(4)I(2) coordination geometry. The dihedral angle between the least-squares planes of the two bpym ligands (r.m.s deviation for all non-H atoms = 0.063?Å) is 85.04?(6)°. In the crystal, complex mol-ecules are connected by C-H?N and C-H?I hydrogen bonds, forming a three-dimensional network. Mol-ecules are stacked in columns along the a axis. Along the c axis, successive mol-ecules stack in the opposite directions.

SUBMITTER: Ha K

PROVIDER: S-EPMC3254274 | biostudies-literature | 2012 Jan

REPOSITORIES: biostudies-literature

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cis-Bis(2,2'-bipyrimidine-κN,N)di-iodidomanganese(II).

Ha Kwang K

Acta crystallographica. Section E, Structure reports online 20111203 Pt 1

The asymmetric unit of the title complex, [MnI(2)(C(8)H(6)N(4))(2)], contains one half of a neutral Mn(II) complex, with the entire molecule completed by the application of twofold symmetry. The Mn(II) ion is six-coordinated in a distorted octa-hedral environment defined by four N atoms of the two chelating 2,2'-bipyrimidine (bpym) ligands and two I(-) anions in a cis-N(4)I(2) coordination geometry. The dihedral angle between the least-squares planes of the two bpym ligands (r.m.s deviation for ...[more]

PMID: 22259317

Similar Datasets

cis-(Acetonitrile-?N)aqua-bis-(2,2'-bipyrimidine-?N,N)manganese(II) cis-diaqua-bis-(2,2'-bipyrimidine-?N,N)manganese(II) tetrakis(perchlorate) dihydrate.

Project description:The asymmetric unit of the title compound, [Mn(CH(3)CN)(C(8)H(6)N(4))(2)(H(2)O)][Mn(C(8)H(6)N(4))(2)(H(2)O)(2)](ClO(4))(4)·2H(2)O, contains two distinct cationic Mn(II) complexes, four perchlorate anions and two solvent water mol-ecules. In the two complexes, both Mn(II) ions are six-coordinated in a distorted octa-hedral environment, but one Mn ion has a cis-N(5)O coordination geometry defined by four N atoms of the two chelating 2,2'-bipyrimidine (bpym) ligands, one N atom of a coordinating acetonitrile mol-ecule and one O atom of a water ligand, whereas the other Mn ion has a cis-N(4)O(2) coordination geometry defined by four N atoms of the two bpym ligands and two O atoms of water ligands. In the crystal structure, the complex mol-ecules, anions and solvent water mol-ecules are linked by inter-molecular O-H?O and O-H?N hydrogen bonds. Three of the four perchlorate anions are disordered over two sets of sites in different ratios.

| S-EPMC3120370 | biostudies-literature

cis-Aqua-bis-(2,2'-bipyrimidine-?N,N)iodidomanganese(II) iodide monohydrate.

Project description:The asymmetric unit of the title compound, [MnI(C(8)H(6)N(4))(2)(H(2)O)]I·H(2)O, consists of a cationic Mn(II) complex, an I(-) anion and a solvent water mol-ecule. In the complex, the Mn(II) ion is six-coordinated in a distorted octa-hedral environment defined by four N atoms of the two chelating 2,2'-bipyrimidine (bpym) ligands, one I(-) anion and one O atom of a water ligand. The dihedral angle between the least-squares planes of the two bpym ligands [maximum deviation = 0.092?(7)?Å] is 79.9?(1)°. In the crystal, the complex, anion and solvent water mol-ecule are linked by inter-molecular O-H?O, O-H?I and O-H?N hydrogen bonds.

| S-EPMC3201340 | biostudies-literature

cis-Aqua-bis-(2,2'-bipyrimidine-?N,N)iodidomanganese(II) iodide dihydrate.

Project description:The asymmetric unit of the title compound, [MnI(C(8)H(6)N(4))(2)(H(2)O)]I·2H(2)O, contains a cationic Mn(II) complex, an I(-) anion and two solvent water mol-ecules. In the complex, the Mn(II) ion is six-coordinated in a considerably distorted octa-hedral environment defined by four N atoms of the two chelating 2,2'-bipyrimidine (bpym) ligands, one I(-) anion and one O atom of a water ligand. As a result of the different trans effects of the I and O atoms, the Mn-N bond trans to the I atom is slightly longer than the Mn-N bond trans to the O atom. The dihedral angle between the least-squares planes of the two bpym ligands [maximum deviation = 0.088?(4)?Å] is 76.48?(6)°. In the crystal, the complex cation, the anion and the solvent water mol-ecules are linked by inter-molecular O-H?O, O-H?I and O-H?N hydrogen bonds.

| S-EPMC3201460 | biostudies-literature

cis-Bis(2,2'-bipyrimidine-?N,N)dibromidomanganese(II) nitro-methane monosolvate.

Project description:The asymmetric unit of the title compound, [MnBr(2)(C(8)H(6)N(4))(2)]·CH(3)NO(2), contains one half of a neutral Mn(II) complex and one half of a nitro-methane solvent mol-ecule, the complete mol-ecules being generated by the application of twofold symmetry. In the complex, the Mn(II) ion has a distorted cis-Br(2)N(4) octa-hedral coordination geometry defined by four N atoms of the two chelating 2,2'-bipyrimidine ligands and two Br(-) ions. There are intra- and inter-molecular C-H?Br and C-H?N contacts.

| S-EPMC3100068 | biostudies-literature

cis-Diaqua-bis-(2,2'-bipyrimidine-?N,N)manganese(II) bis-(perchlorate) nitro-methane disolvate monohydrate.

Project description:The asymmetric unit of the title compound, [Mn(C(8)H(6)N(4))(2)(H(2)O)(2)](ClO(4))(2)·2CH(3)NO(2)·H(2)O, contains one half of a cationic Mn(II) complex, a ClO(4) (-) anion, a nitro-methane solvent mol-ecule and one half-mol-ecule of water. The complex mol-ecule and the solvent water mol-ecule are located on a twofold rotation axis. In the complex, the Mn(II) ion has a distorted cis-N(4)O(2) octa-hedral coordination geometry defined by four N atoms of the two chelating 2,2'-bipyrimidine ligands and two O atoms of water mol-ecules. In the crystal, the complex cations, anions and solvent mol-ecules are linked by inter-molecular O-H?N, O-H?O and weak C-H?O hydrogen bonds. The ClO(4) (-) anion is disordered over two sites with a site-occupancy factor of 0.512?(12) for the major component.

| S-EPMC3238608 | biostudies-literature

μ-(2,2'-Bipyrimidine)-bis-[dichlorido-palladium(II)] dimethyl-formamide monosolvate.

Project description:In the title compound, [Pd(2)Cl(4)(C(8)H(6)N(4))]·C(3)H(7)NO, the two Pd(2+) cations have a distorted square-planar coordination sphere and are bridged by a bis-bidentate 2,2'-bipyrimidine ligand. Two terminal chloride anions are also bonded to each of the Pd(2+) cations. The dinuclear complex and the dimethylformamide solvate molecule lie on the inter-section of a twofold rotation axis and a mirror plane, with disorder present in the solvate mol-ecule. There is a slight distortion from the square-planar metal geometry, as indicated by the bite angles of 81.77 (13)° and 91.63 (5)°. The C and O atoms of the solvent mol-ecule are disordered over two sets of sites of equal occupancy.

| S-EPMC3515126 | biostudies-literature

2,2'-Bipyrimidine-1,1'-diium bis-(tri-iodide)-2,2'-bipyrimidine-water (1/2/2).

Project description:In the crystal of the title compound, C(8)H(8)N(4) (2+)·2I(3) (-)·2C(8)H(6)N(4)·2H(2)O, inversion centres are located at the centroids of the central C-C bonds of the cation and the bpym mol-ecules, as well as at the central I atoms of both anions. Inter-molecular O-H?N and N-H?O hydrogen bonds are observed in the crystal structure.

| S-EPMC3201360 | biostudies-literature

(?-2,2'-Bipyrimidine-?N,N:N,N)bis-[triaqua-(sulfato-?O)manganese(II)].

Project description:The title complex, [Mn(2)(SO(4))(2)(C(8)H(6)N(4))(H(2)O)(6)], is the second monoclinic polymorph [De Munno et al. (1995 ?). Inorg. Chem.34, 408-411; Hong et al. (1996 ?). Polyhedron, 15, 447-452]. The asymmetric unit contains two crystallographically independent half-mol-ecules of the binuclear Mn(II) complex; an inversion centre is located at the centroid of each complex. The two Mn(II) atoms in each complex mol-ecules are bridged by a bis-chelating 2,2'-bipyrimidine (bpym) ligand and each Mn(II) atom is six-coordinated in a considerably distorted octa-hedral environment defined by two N atoms of the bridging bpym ligand and four O atoms from one sulfato anionic ligand and three water mol-ecules. In the crystal, the complex mol-ecules are linked by O-H?O hydrogen bonds between the water and sulfato ligands, forming a three-dimensional network.

| S-EPMC3201432 | biostudies-literature

(2,2'-Bipyrimidine-?(2)N(1),N(1'))bis-(thio-cyanato-?N)platinum(II).

Project description:In the title complex, [Pt(NCS)(2)(C(8)H(6)N(4))], the Pt(II) ion is four-coordinated in a distorted square-planar environment defined by two pyrimidine N atoms derived from a chelating 2,2'-bipyrimidine (bpym) ligand and two mutually cis N atoms from two SCN(-) anions. The thio-cyanate ligands are almost linear, displaying N-C-S bond angles of 178.6?(11) and 173.7?(11)°, and the N atoms are slightly bent coordinated to the Pt atom with Pt-N-C bond angles of 172.7?(9) and 160.4?(10)°. In the crystal, mol-ecules are held together by C-H?S hydrogen bonds. Intra-molecular C-H?N hydrogen bonds are also observed.

| S-EPMC3344397 | biostudies-literature

cis-Bis-(2,2'-bipyrid-yl)dicyanato-cobalt(II).

Project description:In the title complex, [Co(NCO)(2)(C(10)H(8)N(2))(2)], the Co atom is coordinated by four N atoms from two 2,2'-bipyridyl ligands and two N atoms from two cyanate anions in a distorted octa-hedral geometry. The Co atom lies on a twofold rotation axis. The average Co-N bond length is 2.126 (7) Å. Weak inter-molecular C-H⋯O inter-actions lead to the formation of a three-dimensional network.

| S-EPMC2960999 | biostudies-literature

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