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Catena-Poly[[trimethyltin(IV)]-?-2-methylbenzoato-?O:O'].

ABSTRACT: The polymeric structure of the title compound, [Sn(CH(3))(3)(C(8)H(7)O(2))](n), is composed of zigzag chains in which the tin(IV) atoms, coordinated by three methyl groups, are bridged by toluene-2-carboxyl-ate ligands via their O atoms. A slightly distorted trigonal-bipyramidal SnC(3)O(2) coordination geometry arises for the metal, with the O atoms in the axial sites. Weak C-H?O hydrogen bonds help to stabilize the packing.

SUBMITTER: Danish M

PROVIDER: S-EPMC2980210 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature

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catena-Poly[[trimethyltin(IV)]-μ-2-methylbenzoato-κO:O'].

Danish Muhammad M Saleem Iram I Ahmad Nazir N Starosta Wojciech W Leciejewicz Janusz J

Acta crystallographica. Section E, Structure reports online 20091204 Pt 1

The polymeric structure of the title compound, [Sn(CH(3))(3)(C(8)H(7)O(2))](n), is composed of zigzag chains in which the tin(IV) atoms, coordinated by three methyl groups, are bridged by toluene-2-carboxyl-ate ligands via their O atoms. A slightly distorted trigonal-bipyramidal SnC(3)O(2) coordination geometry arises for the metal, with the O atoms in the axial sites. Weak C-H⋯O hydrogen bonds help to stabilize the packing. ...[more]

PMID: 21579938

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