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Sodium N,2-dichloro-benzene-sulfonamidate sesquihydrate.

ABSTRACT: In the title compound, Na(+)·C(6)H(4)Cl(2)NO(2)S(-)·1.5H(2)O, one of the water mol-ecules lies on a twofold axis. There is no inter-action between the N atom and the sodium ion. The sodium ion exhibits a pseudo-octa-hedral coordination defined by three water O atoms and three sulfonyl O atoms from three different anions. The S-N distance of 1.588?(2)?Å is consistent with an S=N double bond. The crystal structure is stabilized by O-H?N and O-H?Cl hydrogen bonds.

SUBMITTER: Gowda BT

PROVIDER: S-EPMC2984040 | biostudies-literature | 2010 Mar

REPOSITORIES: biostudies-literature

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Sodium N,2-dichloro-benzene-sulfonamidate sesquihydrate.

Gowda B Thimme BT Foro Sabine S Shakuntala K K Fuess Hartmut H

Acta crystallographica. Section E, Structure reports online 20100320 Pt 4

In the title compound, Na(+)·C(6)H(4)Cl(2)NO(2)S(-)·1.5H(2)O, one of the water mol-ecules lies on a twofold axis. There is no inter-action between the N atom and the sodium ion. The sodium ion exhibits a pseudo-octa-hedral coordination defined by three water O atoms and three sulfonyl O atoms from three different anions. The S-N distance of 1.588 (2) Å is consistent with an S=N double bond. The crystal structure is stabilized by O-H⋯N and O-H⋯Cl hydrogen bonds. ...[more]

PMID: 21580706

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Potassium N,2-dichloro-benzene-sulfonamidate sesquihydrate.

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