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Tripyridinium cis-tetra-chlorido-dioxido-molybdate(VI) chloride.

ABSTRACT: In the title compound, (C(5)H(6)N)(3)[MoCl(4)O(2)]Cl, the pyridinium cations are N-H?Cl hydrogen bonded to the anionic [MoCl(4)O(2)](2-) complexes and to the two crystallographically independent chloride anions (located on C2 axes). The Mo(6+) centre adopts a highly distorted octa-hedral geometry, being surrounded by four chloride and two terminal oxide groups. The oxide ligands are mutually cis.

SUBMITTER: Fernandes JA

PROVIDER: S-EPMC3006702 | biostudies-literature | 2010 Jun

REPOSITORIES: biostudies-literature

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Tripyridinium cis-tetra-chlorido-dioxido-molybdate(VI) chloride.

Fernandes José A JA Gomes Ana C AC Figueiredo Sónia S Gago Sandra S Ribeiro-Claro Paulo J A PJ Gonçalves Isabel S IS Almeida Paz Filipe A FA

Acta crystallographica. Section E, Structure reports online 20100626 Pt 7

In the title compound, (C(5)H(6)N)(3)[MoCl(4)O(2)]Cl, the pyridinium cations are N-H⋯Cl hydrogen bonded to the anionic [MoCl(4)O(2)](2-) complexes and to the two crystallographically independent chloride anions (located on C2 axes). The Mo(6+) centre adopts a highly distorted octa-hedral geometry, being surrounded by four chloride and two terminal oxide groups. The oxide ligands are mutually cis. ...[more]

PMID: 21587767

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