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Catena-Poly[[(nitrato-?O,O')silver(I)]-?-N,N'-bis-(3-pyridyl-methyl-idene)benzene-1,4-diamine].

ABSTRACT: In the title compound, [Ag(NO(3))(C(18)H(14)N(4))](n), the Ag(I) atom is coordinated by two N atoms from two N,N'-bis-(3-pyridyl-methyl-idene)benzene-1,4-diamine (bpbd) mol-ecules and two O atoms from a bidentate nitrate anion. The bpbd mol-ecules bridge the Ag atoms into a chain. Two adjacent chains are further connected by Ag?Ag inter-actions [3.1631?(8)?Å], forming a double-chain structure. A ?-? inter-action [centroid-centroid distance = 3.758?(3)?Å] occurs between the double chains. Inter-chain C-H?O hydrogen bonds are observed.

SUBMITTER: Liu YH

PROVIDER: S-EPMC3007296 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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catena-Poly[[(nitrato-κO,O')silver(I)]-μ-N,N'-bis-(3-pyridyl-methyl-idene)benzene-1,4-diamine].

Liu Yong-Hao YH Xu Quan Q Han Zhi-You ZY

Acta crystallographica. Section E, Structure reports online 20100707 Pt 8

In the title compound, [Ag(NO(3))(C(18)H(14)N(4))](n), the Ag(I) atom is coordinated by two N atoms from two N,N'-bis-(3-pyridyl-methyl-idene)benzene-1,4-diamine (bpbd) mol-ecules and two O atoms from a bidentate nitrate anion. The bpbd mol-ecules bridge the Ag atoms into a chain. Two adjacent chains are further connected by Ag⋯Ag inter-actions [3.1631 (8) Å], forming a double-chain structure. A π-π inter-action [centroid-centroid distance = 3.758 (3) Å] occurs between the double chains. Inter-c ...[more]

PMID: 21588144

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