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Bis(1,1,2,2-tetramethyldiphosphane-1,2-dithione-?S,S')gold(I) trifluoro-methane-sulfonate.

ABSTRACT: In the title compound, [Au(C(4)H(12)P(2)S(2))(2)](CF(3)SO(3)), the gold(I) atom is tightly bonded to two S atoms belonging to different ligand mol-ecules and forms two weaker contacts to the remaining S atoms. The coordination geometry around gold is inter-mediate between linear-dicoordinate and tetra-hedral with an S-Au-S angle of 161.49?(3)°.

SUBMITTER: Strasser CE

PROVIDER: S-EPMC3007517 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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Bis(1,1,2,2-tetramethyldiphosphane-1,2-dithione-κS,S')gold(I) trifluoro-methane-sulfonate.

Strasser Christoph E CE Cronje Stephanie S Raubenheimer Helgard G HG

Acta crystallographica. Section E, Structure reports online 20100731 Pt 8

In the title compound, [Au(C(4)H(12)P(2)S(2))(2)](CF(3)SO(3)), the gold(I) atom is tightly bonded to two S atoms belonging to different ligand mol-ecules and forms two weaker contacts to the remaining S atoms. The coordination geometry around gold is inter-mediate between linear-dicoordinate and tetra-hedral with an S-Au-S angle of 161.49 (3)°. ...[more]

PMID: 21588101

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