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Benzoyl-dicarbon-yl(η-inden-yl)ruthenium(II).

ABSTRACT: In the title mol-ecule, [Ru(C(9)H(7))(C(7)H(5)O)(CO)(2)], the dihedral angle between the mean plane of the indene ring system and the phenyl ring is 86.28 (8)°. The crystal structure is stabilized by weak inter-molecular C-H⋯O and C-H⋯π(arene) inter-actions. The Ru-η(5)-cyclopentadienyl centroid bond length is 1.946 (11) Å

SUBMITTER: Oudenhoven TA

PROVIDER: S-EPMC3007885 | biostudies-literature | 2010 Aug

REPOSITORIES: biostudies-literature

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Benzoyl-dicarbon-yl(η-inden-yl)ruthenium(II).

Oudenhoven Tracey A TA Walder Brennan J BJ Golen James A JA Rheingold Arnold L AL D'Acchioli Jason S JS

Acta crystallographica. Section E, Structure reports online 20100825 Pt 9

In the title mol-ecule, [Ru(C(9)H(7))(C(7)H(5)O)(CO)(2)], the dihedral angle between the mean plane of the indene ring system and the phenyl ring is 86.28 (8)°. The crystal structure is stabilized by weak inter-molecular C-H⋯O and C-H⋯π(arene) inter-actions. The Ru-η(5)-cyclopentadienyl centroid bond length is 1.946 (11) Å ...[more]

PMID: 21588552

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