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Di-?-iodido-bis{[hydroxy(methoxy)bis(2-pyridyl)methane-?N,O,N']iodidocadmium(II)}.

ABSTRACT: In the centrosymmetric dinuclear title compound, [Cd(2)I(4)(C(12)H(12)N(2)O(2))(2)], two ?-I atoms bridge two Cd(II) atoms and each Cd(II) atom is also bonded to a terminal I atom and a hy-droxy-meth-oxy-bis-(2-pyrid-yl)methane ligand, which functions in an N,O,N'-tridentate mode, resulting in a distorted octa-hedral coordination environment. Inter-molecular O-H?I hydrogen bonds and ?-? stacking inter-actions between the pyridine rings [centroid-centroid distance = 3.790?(2)?Å] are present in the crystal structure.

SUBMITTER: Esmhosseini M 

PROVIDER: S-EPMC3009326 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature

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Di-μ-iodido-bis{[hydroxy(methoxy)bis(2-pyridyl)methane-κN,O,N']iodidocadmium(II)}.

Esmhosseini Majid M   Safari Nasser N   Amani Vahid V  

Acta crystallographica. Section E, Structure reports online 20101023 Pt 11

In the centrosymmetric dinuclear title compound, [Cd(2)I(4)(C(12)H(12)N(2)O(2))(2)], two μ-I atoms bridge two Cd(II) atoms and each Cd(II) atom is also bonded to a terminal I atom and a hy-droxy-meth-oxy-bis-(2-pyrid-yl)methane ligand, which functions in an N,O,N'-tridentate mode, resulting in a distorted octa-hedral coordination environment. Inter-molecular O-H⋯I hydrogen bonds and π-π stacking inter-actions between the pyridine rings [centroid-centroid distance = 3.790 (2) Å] are present in th  ...[more]

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