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Monoclinic form of (cyanato-?N){2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-?O,N,N',O'}manganese(III).

ABSTRACT: The title compound, [Mn(C(16)H(14)N(2)O(2))(NCO)], is a monoclinic polymorph of the previously published ortho-rhom-bic form [Lu et al. (2006 ?). Inorg. Chem.45, 3538-3548]. The Mn(III) ion is chelated by a tetra-dentate Schiff base ligand and coordinated by the N atom of a cyanate ligand in a distorted square-pyramidal arrangement. In the crystal, there are short inter-molecular Mn?O(phenolate) distances of 2.752?(3)?Å between pairs of inversion-related mol-ecules.

SUBMITTER: Zhang D

PROVIDER: S-EPMC3011716 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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Monoclinic form of (cyanato-κN){2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}manganese(III).

Zhang Daopeng D

Acta crystallographica. Section E, Structure reports online 20101124 Pt 12

The title compound, [Mn(C(16)H(14)N(2)O(2))(NCO)], is a monoclinic polymorph of the previously published ortho-rhom-bic form [Lu et al. (2006 ▶). Inorg. Chem.45, 3538-3548]. The Mn(III) ion is chelated by a tetra-dentate Schiff base ligand and coordinated by the N atom of a cyanate ligand in a distorted square-pyramidal arrangement. In the crystal, there are short inter-molecular Mn⋯O(phenolate) distances of 2.752 (3) Å between pairs of inversion-related mol-ecules. ...[more]

PMID: 21589321

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